Optimization of direct conversion of methane to liquid fuels over Cu loaded W/ZSM-5 catalyst

Nor Aishah Saidina Amin; Didi Dwi Anggoro

doi:10.1016/j.fuel.2003.09.013

Optimization of direct conversion of methane to liquid fuels over Cu loaded W/ZSM-5 catalyst

Nor Aishah Saidina Amin^*
, Didi Dwi Anggoro

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

The optimization of methane conversion to liquid fuels over copper loaded W/ZSM-5 catalyst was studied by utilizing experimental design from 'Statsoft Statistica' version 6.0 software. Response surface methodology was employed to determine the optimum methane conversion and C₅⁺ selectivity. Numerical results indicated the optimum methane conversion of 29. 4% with the corresponding C₅⁺ selectivity of 57.2% were achieved at 12.3vol% of O₂, 203.9 ml/min of total feed flow rate, and %W doped of 3.2wt%. The optimum C₅⁺ selectivity of 70.2% was attained at 7.6vol% of O₂, 208.9 ml/min of total feed flow rate, and 3.2wt% of W content with the corresponding methane conversion of 26.7%. By means of variance analysis and additional experiments, the adequacy of this model is confirmed.

Original language	English
Pages (from-to)	487-494
Number of pages	8
Journal	Fuel
Volume	83
Issue number	4-5
DOIs	https://doi.org/10.1016/j.fuel.2003.09.013
State	Published - Mar 2004
Externally published	Yes

Keywords

Direct conversion
Liquid fuels
Methane
Optimization

ASJC Scopus subject areas

General Chemical Engineering
Fuel Technology
Energy Engineering and Power Technology
Organic Chemistry

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10.1016/j.fuel.2003.09.013

Cite this

@article{c19c00046eb248c29fdfa6d61c26247e,

title = "Optimization of direct conversion of methane to liquid fuels over Cu loaded W/ZSM-5 catalyst",

abstract = "The optimization of methane conversion to liquid fuels over copper loaded W/ZSM-5 catalyst was studied by utilizing experimental design from 'Statsoft Statistica' version 6.0 software. Response surface methodology was employed to determine the optimum methane conversion and C5+ selectivity. Numerical results indicated the optimum methane conversion of 29. 4\% with the corresponding C5+ selectivity of 57.2\% were achieved at 12.3vol\% of O2, 203.9 ml/min of total feed flow rate, and \%W doped of 3.2wt\%. The optimum C5+ selectivity of 70.2\% was attained at 7.6vol\% of O2, 208.9 ml/min of total feed flow rate, and 3.2wt\% of W content with the corresponding methane conversion of 26.7\%. By means of variance analysis and additional experiments, the adequacy of this model is confirmed.",

keywords = "Direct conversion, Liquid fuels, Methane, Optimization",

author = "Amin, \{Nor Aishah Saidina\} and Anggoro, \{Didi Dwi\}",

year = "2004",

month = mar,

doi = "10.1016/j.fuel.2003.09.013",

language = "English",

volume = "83",

pages = "487--494",

journal = "Fuel",

issn = "0016-2361",

publisher = "Elsevier BV",

number = "4-5",

}

TY - JOUR

T1 - Optimization of direct conversion of methane to liquid fuels over Cu loaded W/ZSM-5 catalyst

AU - Amin, Nor Aishah Saidina

AU - Anggoro, Didi Dwi

PY - 2004/3

Y1 - 2004/3

N2 - The optimization of methane conversion to liquid fuels over copper loaded W/ZSM-5 catalyst was studied by utilizing experimental design from 'Statsoft Statistica' version 6.0 software. Response surface methodology was employed to determine the optimum methane conversion and C5+ selectivity. Numerical results indicated the optimum methane conversion of 29. 4% with the corresponding C5+ selectivity of 57.2% were achieved at 12.3vol% of O2, 203.9 ml/min of total feed flow rate, and %W doped of 3.2wt%. The optimum C5+ selectivity of 70.2% was attained at 7.6vol% of O2, 208.9 ml/min of total feed flow rate, and 3.2wt% of W content with the corresponding methane conversion of 26.7%. By means of variance analysis and additional experiments, the adequacy of this model is confirmed.

AB - The optimization of methane conversion to liquid fuels over copper loaded W/ZSM-5 catalyst was studied by utilizing experimental design from 'Statsoft Statistica' version 6.0 software. Response surface methodology was employed to determine the optimum methane conversion and C5+ selectivity. Numerical results indicated the optimum methane conversion of 29. 4% with the corresponding C5+ selectivity of 57.2% were achieved at 12.3vol% of O2, 203.9 ml/min of total feed flow rate, and %W doped of 3.2wt%. The optimum C5+ selectivity of 70.2% was attained at 7.6vol% of O2, 208.9 ml/min of total feed flow rate, and 3.2wt% of W content with the corresponding methane conversion of 26.7%. By means of variance analysis and additional experiments, the adequacy of this model is confirmed.

KW - Direct conversion

KW - Liquid fuels

KW - Methane

KW - Optimization

UR - https://www.scopus.com/pages/publications/0344877481

U2 - 10.1016/j.fuel.2003.09.013

DO - 10.1016/j.fuel.2003.09.013

M3 - Article

AN - SCOPUS:0344877481

SN - 0016-2361

VL - 83

SP - 487

EP - 494

JO - Fuel

JF - Fuel

IS - 4-5

ER -

Optimization of direct conversion of methane to liquid fuels over Cu loaded W/ZSM-5 catalyst

Abstract

Keywords

ASJC Scopus subject areas

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