Onsite ammonia synthesis from water vapor and nitrogen in the air

Xiaowei Song, Chanbasha Basheer*, Jinheng Xu, Richard N. Zare*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

An innovative method for onsite ammonia synthesis under ambient conditions has been developed using a catalyst mesh composed of magnetite (Fe3O4) and Nafion polymer. We pass air through the catalyst, which condenses microdroplets from atmospheric water vapor and uses nitrogen from the air, resulting in ammonia concentrations ranging from 25 to 120 μM in 1 hour, depending on local relative humidity. Operated at room temperature and atmospheric pressure, this technique eliminates the need for additional electricity or radiation, thereby substantially reducing carbon dioxide emissions compared to the traditional Haber-Bosch process. In laboratory experiments, we further optimized the reaction conditions and scaled up the process. After 2 hours of spraying, the ammonia concentration increased to 270.2 ± 25.1 μM. In addition, we present a portable device designed for onsite ammonia production which consistently produces an ammonia concentration that is adequate for some agricultural irrigation purposes.

Original languageEnglish
Article numbereads4443
JournalScience advances
Volume10
Issue number50
DOIs
StatePublished - 13 Dec 2024

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ASJC Scopus subject areas

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