One-step Formation of Urea from Carbon Dioxide and Nitrogen Using Water Microdroplets

Xiaowei Song, Chanbasha Basheer*, Yu Xia, Juan Li, Ismail Abdulazeez, Abdulaziz A. Al-Saadi, Mohammad Mofidfar, Mohammed Altahir Suliman, Richard N. Zare*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

Water (H2O) microdroplets are sprayed onto a graphite mesh covered with a CuBi2O4 coating using a 1:1 mixture of N2 and CO2 as the nebulizing gas. The resulting microdroplets contain urea [CO(NH2)2] as detected by both mass spectrometry and 13C nuclear magnetic resonance. This gas-liquid-solid heterogeneous catalytic system synthesizes urea in one step on the 0.1 ms time scale. The conversion rate reaches 2.7 mmol g-1 h-1 at 25 °C and 12.3 mmol g-1 h-1 at 65 °C, with no external voltage applied. Water microdroplets serve as the hydrogen source and the electron transfer medium for N2 and CO2 in contact with CuBi2O4. Water-gas and water-solid contact electrification are speculated to drive the reaction process. This strategy couples N2 fixation and CO2 utilization in an ecofriendly process to produce urea, converting a greenhouse gas into a value-added product.

Original languageEnglish
Pages (from-to)25910-25916
Number of pages7
JournalJournal of the American Chemical Society
Volume145
Issue number47
DOIs
StatePublished - 29 Nov 2023

Bibliographical note

Publisher Copyright:
© 2023 American Chemical Society

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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