One-pot liquid microwave-assisted green synthesis of neutral trans-Cl2Cu(NNOH)2: XRD/HSA-interactions, antifungal and antibacterial evaluations

Abderrahim Titi; Ismail Warad; Saud M. Almutairi; Mohammed Fettouhi; Mouslim Messali; Ateyatallah Aljuhani; Rachid Touzani; Abdelkader Zarrouk

doi:10.1016/j.inoche.2020.108292

One-pot liquid microwave-assisted green synthesis of neutral trans-Cl₂Cu(NNOH)₂: XRD/HSA-interactions, antifungal and antibacterial evaluations

Abderrahim Titi^*
, Ismail Warad
, Saud M. Almutairi
, Mohammed Fettouhi
, Mouslim Messali
, Ateyatallah Aljuhani
, Rachid Touzani
, Abdelkader Zarrouk

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

10 Scopus citations

Abstract

In the present work, the ethyl-1-(hydroxymethyl)-5-methy-3-carboxylatel pyrazole)NNOH(polydentate ligand was used to synthesize a new trans-Cl₂Cu(NNOH)₂ complex via one-port microwave short procedure using water medium with no side products. The complex composition was analyzed based on FT-IR, UV–Vis, CHN-EA and EDX. Its crystal structure was determined by single crystal X-ray diffraction analysis. Hirshfeld surface analysis (HSA) and two-dimension figure-print (2D-FP) for the complex have been performed. The antibacterial activities were investigated using four types of gram-negative and gram-positive bacteria. Furthermore, the antifungal activities were evaluated using four types of fungi.

Original language	English
Article number	108292
Journal	Inorganic Chemistry Communication
Volume	122
DOIs	https://doi.org/10.1016/j.inoche.2020.108292
State	Published - Dec 2020

Bibliographical note

Publisher Copyright:
© 2020 Elsevier B.V.

Keywords

Biological activities
Cu(II) complex
Pyrazole
XRD

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.inoche.2020.108292

Cite this

@article{f1ffb05f42ea440683277b77b67d5f20,

title = "One-pot liquid microwave-assisted green synthesis of neutral trans-Cl2Cu(NNOH)2: XRD/HSA-interactions, antifungal and antibacterial evaluations",

abstract = "In the present work, the ethyl-1-(hydroxymethyl)-5-methy-3-carboxylatel pyrazole)NNOH(polydentate ligand was used to synthesize a new trans-Cl2Cu(NNOH)2 complex via one-port microwave short procedure using water medium with no side products. The complex composition was analyzed based on FT-IR, UV–Vis, CHN-EA and EDX. Its crystal structure was determined by single crystal X-ray diffraction analysis. Hirshfeld surface analysis (HSA) and two-dimension figure-print (2D-FP) for the complex have been performed. The antibacterial activities were investigated using four types of gram-negative and gram-positive bacteria. Furthermore, the antifungal activities were evaluated using four types of fungi.",

keywords = "Biological activities, Cu(II) complex, Pyrazole, XRD",

author = "Abderrahim Titi and Ismail Warad and Almutairi, \{Saud M.\} and Mohammed Fettouhi and Mouslim Messali and Ateyatallah Aljuhani and Rachid Touzani and Abdelkader Zarrouk",

note = "Publisher Copyright: {\textcopyright} 2020 Elsevier B.V.",

year = "2020",

month = dec,

doi = "10.1016/j.inoche.2020.108292",

language = "English",

volume = "122",

journal = "Inorganic Chemistry Communication",

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TY - JOUR

T1 - One-pot liquid microwave-assisted green synthesis of neutral trans-Cl2Cu(NNOH)2

T2 - XRD/HSA-interactions, antifungal and antibacterial evaluations

AU - Titi, Abderrahim

AU - Warad, Ismail

AU - Almutairi, Saud M.

AU - Fettouhi, Mohammed

AU - Messali, Mouslim

AU - Aljuhani, Ateyatallah

AU - Touzani, Rachid

AU - Zarrouk, Abdelkader

PY - 2020/12

Y1 - 2020/12

N2 - In the present work, the ethyl-1-(hydroxymethyl)-5-methy-3-carboxylatel pyrazole)NNOH(polydentate ligand was used to synthesize a new trans-Cl2Cu(NNOH)2 complex via one-port microwave short procedure using water medium with no side products. The complex composition was analyzed based on FT-IR, UV–Vis, CHN-EA and EDX. Its crystal structure was determined by single crystal X-ray diffraction analysis. Hirshfeld surface analysis (HSA) and two-dimension figure-print (2D-FP) for the complex have been performed. The antibacterial activities were investigated using four types of gram-negative and gram-positive bacteria. Furthermore, the antifungal activities were evaluated using four types of fungi.

AB - In the present work, the ethyl-1-(hydroxymethyl)-5-methy-3-carboxylatel pyrazole)NNOH(polydentate ligand was used to synthesize a new trans-Cl2Cu(NNOH)2 complex via one-port microwave short procedure using water medium with no side products. The complex composition was analyzed based on FT-IR, UV–Vis, CHN-EA and EDX. Its crystal structure was determined by single crystal X-ray diffraction analysis. Hirshfeld surface analysis (HSA) and two-dimension figure-print (2D-FP) for the complex have been performed. The antibacterial activities were investigated using four types of gram-negative and gram-positive bacteria. Furthermore, the antifungal activities were evaluated using four types of fungi.

KW - Biological activities

KW - Cu(II) complex

KW - Pyrazole

KW - XRD

UR - https://www.scopus.com/pages/publications/85094559451

U2 - 10.1016/j.inoche.2020.108292

DO - 10.1016/j.inoche.2020.108292

M3 - Review article

AN - SCOPUS:85094559451

SN - 1387-7003

VL - 122

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

M1 - 108292

ER -