TY - JOUR
T1 - One-pot electrochemical synthesis of palladium nanoparticles and their application in the Suzuki reaction
AU - Deshmukh, Krishna M.
AU - Qureshi, Ziyauddin S.
AU - Bhatte, Kushal D.
AU - Venkatesan, K. A.
AU - Srinivasan, T. G.
AU - Rao, P. R.Vasudeva
AU - Bhanage, Bhalchandra M.
PY - 2011/12
Y1 - 2011/12
N2 - A novel potential controllable, template free, electrodeposition/synthesis of palladium nanoparticles on an electrode surface as well as in the bulk electrolyte using ionic liquid as an electrolyte cum stabilizer is reported for the first time. The present method of preparation of palladium nanoparticles is advantageous as it eliminates the requirement of additional stabilizers or capping agents. The prepared palladium nanoparticles are characterized by different techniques such as TEM, SEM, EDAX and XPS analyses. These nanoparticles exhibited high catalytic activity for the Suzuki coupling reaction of unactivated halides in aqueous media with high TON.
AB - A novel potential controllable, template free, electrodeposition/synthesis of palladium nanoparticles on an electrode surface as well as in the bulk electrolyte using ionic liquid as an electrolyte cum stabilizer is reported for the first time. The present method of preparation of palladium nanoparticles is advantageous as it eliminates the requirement of additional stabilizers or capping agents. The prepared palladium nanoparticles are characterized by different techniques such as TEM, SEM, EDAX and XPS analyses. These nanoparticles exhibited high catalytic activity for the Suzuki coupling reaction of unactivated halides in aqueous media with high TON.
UR - https://www.scopus.com/pages/publications/81855206298
U2 - 10.1039/c1nj20638a
DO - 10.1039/c1nj20638a
M3 - Article
AN - SCOPUS:81855206298
SN - 1144-0546
VL - 35
SP - 2747
EP - 2751
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 12
ER -