O-Acetyl-N-(o-hydroxybenzyl)-N-isopropylhydroxylamine

M. Sakhawat Hussain; M. Ul-Haque

doi:10.1107/s0108270196003332

O-Acetyl-N-(o-hydroxybenzyl)-N-isopropylhydroxylamine

M. Sakhawat Hussain^*
, M. Ul-Haque

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Although the solution chemistry of hydroxylamine derivatives is well documented, literature on the conformational aspects in the solid state is rather scarce. The structure of the title compound, C₁₂H₁₇NO₃, revealed an N4-O1-C15-O2 torsion angle of -6.0 (7)° indicating a cis and planar disposition of N-O and C-O bonds. This is the most stable and only observable conformer, as opposed to the trans and planar arrangement.

Original language	English
Pages (from-to)	2343-2345
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	9
DOIs	https://doi.org/10.1107/s0108270196003332
State	Published - 15 Sep 1996
Externally published	Yes

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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title = "O-Acetyl-N-(o-hydroxybenzyl)-N-isopropylhydroxylamine",

abstract = "Although the solution chemistry of hydroxylamine derivatives is well documented, literature on the conformational aspects in the solid state is rather scarce. The structure of the title compound, C12H17NO3, revealed an N4-O1-C15-O2 torsion angle of -6.0 (7)° indicating a cis and planar disposition of N-O and C-O bonds. This is the most stable and only observable conformer, as opposed to the trans and planar arrangement.",

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year = "1996",

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doi = "10.1107/s0108270196003332",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - O-Acetyl-N-(o-hydroxybenzyl)-N-isopropylhydroxylamine

AU - Sakhawat Hussain, M.

AU - Ul-Haque, M.

PY - 1996/9/15

Y1 - 1996/9/15

N2 - Although the solution chemistry of hydroxylamine derivatives is well documented, literature on the conformational aspects in the solid state is rather scarce. The structure of the title compound, C12H17NO3, revealed an N4-O1-C15-O2 torsion angle of -6.0 (7)° indicating a cis and planar disposition of N-O and C-O bonds. This is the most stable and only observable conformer, as opposed to the trans and planar arrangement.

AB - Although the solution chemistry of hydroxylamine derivatives is well documented, literature on the conformational aspects in the solid state is rather scarce. The structure of the title compound, C12H17NO3, revealed an N4-O1-C15-O2 torsion angle of -6.0 (7)° indicating a cis and planar disposition of N-O and C-O bonds. This is the most stable and only observable conformer, as opposed to the trans and planar arrangement.

UR - https://www.scopus.com/pages/publications/3743145025

U2 - 10.1107/s0108270196003332

DO - 10.1107/s0108270196003332

M3 - Article

AN - SCOPUS:3743145025

SN - 0108-2701

VL - 52

SP - 2343

EP - 2345

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 9

ER -

O-Acetyl-N-(o-hydroxybenzyl)-N-isopropylhydroxylamine

Abstract

ASJC Scopus subject areas

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