Novel Z-scheme Binary Zinc Tungsten Oxide/Nickel Ferrite Nanohybrids for Photocatalytic Reduction of Chromium (Cr (VI)), Photoelectrochemical Water Splitting and Degradation of Toxic Organic Pollutants

A simple hydrothermal approach was demonstrated for synthesizing a coupled NiFe₂O₄-ZnWO₄ nanocomposite, wherein one-dimensional ZnWO₄ nanorods were inserted into two-dimensional NiFe₂O₄ nanoplates. Herein, we evaluated the photocatalytic removal of Cr(VI), and degradation of tetracycline (TC) and methylene blue (MB) by the nanocomposite, as well as its ability to split water. The ZnWO₄ nanorods enriched the synergistic interactions, upgraded the solar light fascination proficiency, and demonstrated outstanding detachment and migration of the photogenerated charges, as confirmed by a transient photocurrent study and electrochemical impedance spectroscopy measurements. Compared to pristine NiFe₂O₄ and ZnWO_4, the NiFe₂O₄-ZnWO₄ nanocomposite exhibited a higher Cr(VI) reduction (93.5%) and removal of TC (97.9%) and MB (99.6%). Radical trapping results suggested that hydroxyl and superoxide species are dominant reactive species, thereby facilitating the Z-scheme mechanism. Furthermore, a probable photocatalytic mechanism was projected based on the experimental results. The photoelectrochemical analysis confirmed that NiFe₂O₄-ZnWO₄ exhibited minor charge-transfer resistance and large photocurrents. We propose a novel and efficient approach for designing a coupled heterostructured nanocomposites with a significant solar light ability for ecological conservation and water splitting.