New modified mesoporous silica nanoparticles with bimetallic Ni-Zr for electroanalytical detection of dopamine

Mohamad Rafizie Aiman Mohamed Roduan; Mohamad Idris Saidin; Siti Munirah Sidik; Jaafar Abdullah; Illyas Md Isa; Norhayati Hashim; Mohamad Syahrizal Ahmad; Siti Nur Akmar Mohd Yazid; Anwar Ul-Hamid; Aireen Aina Bahari

doi:10.5599/jese.1200

New modified mesoporous silica nanoparticles with bimetallic Ni-Zr for electroanalytical detection of dopamine

Mohamad Rafizie Aiman Mohamed Roduan, Mohamad Idris Saidin^*, Siti Munirah Sidik, Jaafar Abdullah, Illyas Md Isa, Norhayati Hashim, Mohamad Syahrizal Ahmad, Siti Nur Akmar Mohd Yazid, Anwar Ul-Hamid, Aireen Aina Bahari

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

In this research, bimetallic nickel-zirconia supported on mesoporous nanoparticles (Ni-Zr/MSN) were successfully synthesized by a simple in situ electrolysis method. Ni-Zr/MSN were well-characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) analyzer, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Ni-Zr/MSN were then cast onto a modified glassy carbon electrode (Ni-Zr/MSN/GCE) as dopamine (DA) sensor. Under optimal conditions, the sensor showed a linear concen-tration relationship in the range of 0.3 µM–0.1 mM with a limit of detection of 0.13 µM. The relative standard deviation for 0.1 mM DA solution was 2.1 % (n = 5). The presence of excess catechol, saccharose, glycine, lactose, uric acid, and Cr³⁺, Fe²⁺ and Na⁺ as interferents was negligible, except for uric acid in 10-fold excess. The analytical recovery of the sensor was successfully demonstrated by the determination of DA in DA-containing medicine and wastewater samples. The results presented herein provide new perspectives on Ni-Zr/MSN as a potential nanomaterial in the development of DA sensors.

Original language	English
Pages (from-to)	463-474
Number of pages	12
Journal	Journal of Electrochemical Science and Engineering
Volume	12
Issue number	3
DOIs	https://doi.org/10.5599/jese.1200
State	Published - 13 Jun 2022

Bibliographical note

Publisher Copyright:
© 2022 by the authors; licensee IAPC, Zagreb, Croatia.

Keywords

3,4-Dihydroxyphenethylamine
Porous material
electrochemical sensor
modified GC electrode
nickel-zirconia
silica nanoparticles

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Colloid and Surface Chemistry
Materials Chemistry
Electrochemistry

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Roduan, M. R. A. M., Saidin, M. I., Sidik, S. M., Abdullah, J., Isa, I. M., Hashim, N., Ahmad, M. S., Yazid, S. N. A. M., Ul-Hamid, A., & Bahari, A. A. (2022). New modified mesoporous silica nanoparticles with bimetallic Ni-Zr for electroanalytical detection of dopamine. Journal of Electrochemical Science and Engineering, 12(3), 463-474. https://doi.org/10.5599/jese.1200

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title = "New modified mesoporous silica nanoparticles with bimetallic Ni-Zr for electroanalytical detection of dopamine",

abstract = "In this research, bimetallic nickel-zirconia supported on mesoporous nanoparticles (Ni-Zr/MSN) were successfully synthesized by a simple in situ electrolysis method. Ni-Zr/MSN were well-characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) analyzer, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Ni-Zr/MSN were then cast onto a modified glassy carbon electrode (Ni-Zr/MSN/GCE) as dopamine (DA) sensor. Under optimal conditions, the sensor showed a linear concen-tration relationship in the range of 0.3 µM–0.1 mM with a limit of detection of 0.13 µM. The relative standard deviation for 0.1 mM DA solution was 2.1 % (n = 5). The presence of excess catechol, saccharose, glycine, lactose, uric acid, and Cr3+, Fe2+ and Na+ as interferents was negligible, except for uric acid in 10-fold excess. The analytical recovery of the sensor was successfully demonstrated by the determination of DA in DA-containing medicine and wastewater samples. The results presented herein provide new perspectives on Ni-Zr/MSN as a potential nanomaterial in the development of DA sensors.",

keywords = "3,4-Dihydroxyphenethylamine, Porous material, electrochemical sensor, modified GC electrode, nickel-zirconia, silica nanoparticles",

author = "Roduan, {Mohamad Rafizie Aiman Mohamed} and Saidin, {Mohamad Idris} and Sidik, {Siti Munirah} and Jaafar Abdullah and Isa, {Illyas Md} and Norhayati Hashim and Ahmad, {Mohamad Syahrizal} and Yazid, {Siti Nur Akmar Mohd} and Anwar Ul-Hamid and Bahari, {Aireen Aina}",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors; licensee IAPC, Zagreb, Croatia.",

year = "2022",

month = jun,

day = "13",

doi = "10.5599/jese.1200",

language = "English",

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T1 - New modified mesoporous silica nanoparticles with bimetallic Ni-Zr for electroanalytical detection of dopamine

AU - Roduan, Mohamad Rafizie Aiman Mohamed

AU - Saidin, Mohamad Idris

AU - Sidik, Siti Munirah

AU - Abdullah, Jaafar

AU - Isa, Illyas Md

AU - Hashim, Norhayati

AU - Ahmad, Mohamad Syahrizal

AU - Yazid, Siti Nur Akmar Mohd

AU - Ul-Hamid, Anwar

AU - Bahari, Aireen Aina

PY - 2022/6/13

Y1 - 2022/6/13

N2 - In this research, bimetallic nickel-zirconia supported on mesoporous nanoparticles (Ni-Zr/MSN) were successfully synthesized by a simple in situ electrolysis method. Ni-Zr/MSN were well-characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) analyzer, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Ni-Zr/MSN were then cast onto a modified glassy carbon electrode (Ni-Zr/MSN/GCE) as dopamine (DA) sensor. Under optimal conditions, the sensor showed a linear concen-tration relationship in the range of 0.3 µM–0.1 mM with a limit of detection of 0.13 µM. The relative standard deviation for 0.1 mM DA solution was 2.1 % (n = 5). The presence of excess catechol, saccharose, glycine, lactose, uric acid, and Cr3+, Fe2+ and Na+ as interferents was negligible, except for uric acid in 10-fold excess. The analytical recovery of the sensor was successfully demonstrated by the determination of DA in DA-containing medicine and wastewater samples. The results presented herein provide new perspectives on Ni-Zr/MSN as a potential nanomaterial in the development of DA sensors.

AB - In this research, bimetallic nickel-zirconia supported on mesoporous nanoparticles (Ni-Zr/MSN) were successfully synthesized by a simple in situ electrolysis method. Ni-Zr/MSN were well-characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) analyzer, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM). Ni-Zr/MSN were then cast onto a modified glassy carbon electrode (Ni-Zr/MSN/GCE) as dopamine (DA) sensor. Under optimal conditions, the sensor showed a linear concen-tration relationship in the range of 0.3 µM–0.1 mM with a limit of detection of 0.13 µM. The relative standard deviation for 0.1 mM DA solution was 2.1 % (n = 5). The presence of excess catechol, saccharose, glycine, lactose, uric acid, and Cr3+, Fe2+ and Na+ as interferents was negligible, except for uric acid in 10-fold excess. The analytical recovery of the sensor was successfully demonstrated by the determination of DA in DA-containing medicine and wastewater samples. The results presented herein provide new perspectives on Ni-Zr/MSN as a potential nanomaterial in the development of DA sensors.

KW - 3,4-Dihydroxyphenethylamine

KW - Porous material

KW - electrochemical sensor

KW - modified GC electrode

KW - nickel-zirconia

KW - silica nanoparticles

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U2 - 10.5599/jese.1200

DO - 10.5599/jese.1200

M3 - Article

AN - SCOPUS:85132541827

SN - 1847-9286

VL - 12

SP - 463

EP - 474

JO - Journal of Electrochemical Science and Engineering

JF - Journal of Electrochemical Science and Engineering

IS - 3

ER -

New modified mesoporous silica nanoparticles with bimetallic Ni-Zr for electroanalytical detection of dopamine

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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