Multi self-healable UV shielding polyurethane/CeO2 protective coating: The effect of low-molecular-weight polyols

Mohammad Mizanur Rahman; Rami Suleiman; Md Hasan Zahir; Aasif Helal; A. Madhan Kumar; Md Bashirul Haq

doi:10.3390/POLYM12091947

Multi self-healable UV shielding polyurethane/CeO₂ protective coating: The effect of low-molecular-weight polyols

Mohammad Mizanur Rahman^*, Rami Suleiman, Md Hasan Zahir, Aasif Helal, A. Madhan Kumar, Md Bashirul Haq^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., M_n = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of M_n 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO₂ was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO₂) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO₂ coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO₂-P) showed similar self-healing properties. The PU-11-3-3-CeO₂-P coating also showed excellent UV shielding in real outdoor exposure conditions.

Original language	English
Article number	1947
Journal	Polymers
Volume	12
Issue number	9
DOIs	https://doi.org/10.3390/POLYM12091947
State	Published - Sep 2020

Bibliographical note

Publisher Copyright:
© 2020 by the authors.

Keywords

Coating
Polyurethane
Self-healing

ASJC Scopus subject areas

General Chemistry
Polymers and Plastics

Access to Document

10.3390/POLYM12091947

Cite this

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title = "Multi self-healable UV shielding polyurethane/CeO2 protective coating: The effect of low-molecular-weight polyols",

abstract = "We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., Mn = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of Mn 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO2 was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO2) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO2 coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO2-P) showed similar self-healing properties. The PU-11-3-3-CeO2-P coating also showed excellent UV shielding in real outdoor exposure conditions.",

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AU - Madhan Kumar, A.

AU - Haq, Md Bashirul

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N2 - We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., Mn = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of Mn 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO2 was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO2) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO2 coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO2-P) showed similar self-healing properties. The PU-11-3-3-CeO2-P coating also showed excellent UV shielding in real outdoor exposure conditions.

AB - We prepared a series of polyurethane (PU) coatings with defined contents using poly(tetramethylene oxide)glycol (PTMG) with two different molecular weights (i.e., Mn = 2000 and 650), as well as polydimethyl siloxane (PDMS) with a molecular weight of Mn 550. For every coating, maximum adhesive strength and excellent self-healing character (three times) were found using 6.775 mol% mixed with low-molecular-weight-based polyols (PU-11-3-3). Defined 1.0 wt% CeO2 was also used for the PU-11-3-3 coating (i.e., PU-11-3-3-CeO2) to obtain UV shielding properties. Both the in situ polymerization and blending processes were separately applied during the preparation of the PU-11-3-3-CeO2 coating dispersion. The in situ polymerization-based coating (i.e., PU-11-3-3-CeO2-P) showed similar self-healing properties. The PU-11-3-3-CeO2-P coating also showed excellent UV shielding in real outdoor exposure conditions.

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