Monitoring and assessment of toxic metals in Gulf War oil spill contaminated soil using laser-induced breakdown spectroscopy

T. Hussain, M. A. Gondal*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

105 Scopus citations

Abstract

Laser-induced breakdown spectroscopy (LIBS) was applied for the detection of toxic metals in oil spill contaminated soil (OSCS). The OSCS samples were collected from Khursania Saudi Arabia along the coast of Persian Gulf exposed to oil spills in 1991 Gulf war. Environmentally important elements like Aluminum Magnesium, Calcium, Chromium, Titanium, Strontium, Iron, Barium, Sodium, potassium, Zirconium and Vanadium from the contaminated soil have been detected. Optimal experimental conditions for analysis were investigated. The LIBS system was calibrated using standard samples containing these trace elements. The results obtained using Laser-Induced Breakdown Spectroscopy (LIBS) were compared with the results obtained using Inductively Coupled Plasma Emission Spectroscopy (ICP). The concentrations of some elements (Ba and Cr) were found higher than permissible safe limits. Health risks associated with exposure to such toxic elements are also discussed.

Original languageEnglish
Pages (from-to)391-399
Number of pages9
JournalEnvironmental Monitoring and Assessment
Volume136
Issue number1-3
DOIs
StatePublished - Jan 2008

Bibliographical note

Funding Information:
Acknowledgements The support by the Physics Departments and King Fahd University of Petroleum and Minerals is gratefully acknowledged. One of the author (T.H.) is thankful to National University of Science and Technology and Government of Pakistan for finacial support for his Ph.D work. He is also thankful to KFUPM for its hospitality and permission to work at its research facilties.

Keywords

  • Environmental effects
  • GulfWar 1991 oil spill disaster
  • Healthrisk assessment
  • LIBS
  • Laser spectroscopy and its applications
  • Multi-elemental analysis
  • Oils pill contaminated soil
  • Trace metals

ASJC Scopus subject areas

  • General Environmental Science
  • Pollution
  • Management, Monitoring, Policy and Law

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