Modelling of CO2 loading in DEA by using peak ratio of Raman spectroscopy

M. Z. Shahid; Abdulhalim Shah Maulud; M. Azmi Bustam

doi:10.4028/www.scientific.net/AMM.625.188

Modelling of CO₂ loading in DEA by using peak ratio of Raman spectroscopy

M. Z. Shahid
, Abdulhalim Shah Maulud^*
, M. Azmi Bustam

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Carbon dioxide (CO₂) capturing has been an important issue for decades. Alkanoamines, such as diethanolamine (DEA) have been widely used for CO₂ separation by absorption process. During this process, CO₂ loading measurement is an imperative action for a proper process control. Currently used methods are titration based which requires a long processing time. In this work Raman spectroscopy is used to model and predict the CO₂ loading in wide range (0-0.97 CO₂ mole/amine mole). The models are developed by using Raman peak ratios to minimize the error due to peaks fluctuations. The Raman peak ratio of 1022 cm^-1/1461cm^-1 has been found as a good fit with the coefficient of determination (R²) of 0.92 and mean squared error (MSE) of 0.00656 CO₂ mole²/ amine mole² in prediction of CO₂ loading.

Original language	English
Title of host publication	Process and Advanced Materials Engineering
Editors	Iqbal Ahmed
Publisher	Trans Tech Publications Ltd
Pages	188-191
Number of pages	4
ISBN (Electronic)	9783038351818
DOIs	https://doi.org/10.4028/www.scientific.net/AMM.625.188
State	Published - 2014
Externally published	Yes

Publication series

Name	Applied Mechanics and Materials
Volume	625
ISSN (Print)	1660-9336
ISSN (Electronic)	1662-7482

Bibliographical note

Publisher Copyright:
© 2014 Trans Tech Publications, Switzerland.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Keywords

CO absorption in alkanolamine
CO loading measurement
Raman spectroscopy

ASJC Scopus subject areas

General Engineering

Access to Document

10.4028/www.scientific.net/AMM.625.188

Cite this

@inproceedings{68d218ef1e144b1ca252f0009978178e,

title = "Modelling of CO2 loading in DEA by using peak ratio of Raman spectroscopy",

abstract = "Carbon dioxide (CO2) capturing has been an important issue for decades. Alkanoamines, such as diethanolamine (DEA) have been widely used for CO2 separation by absorption process. During this process, CO2 loading measurement is an imperative action for a proper process control. Currently used methods are titration based which requires a long processing time. In this work Raman spectroscopy is used to model and predict the CO2 loading in wide range (0-0.97 CO2 mole/amine mole). The models are developed by using Raman peak ratios to minimize the error due to peaks fluctuations. The Raman peak ratio of 1022 cm-1/1461cm-1 has been found as a good fit with the coefficient of determination (R2) of 0.92 and mean squared error (MSE) of 0.00656 CO2 mole2/ amine mole2 in prediction of CO2 loading.",

keywords = "CO absorption in alkanolamine, CO loading measurement, Raman spectroscopy",

author = "Shahid, \{M. Z.\} and Maulud, \{Abdulhalim Shah\} and Bustam, \{M. Azmi\}",

note = "Publisher Copyright: {\textcopyright} 2014 Trans Tech Publications, Switzerland.",

year = "2014",

doi = "10.4028/www.scientific.net/AMM.625.188",

language = "English",

series = "Applied Mechanics and Materials",

publisher = "Trans Tech Publications Ltd",

pages = "188--191",

editor = "Iqbal Ahmed",

booktitle = "Process and Advanced Materials Engineering",

}

Modelling of CO₂ loading in DEA by using peak ratio of Raman spectroscopy. / Shahid, M. Z.; Maulud, Abdulhalim Shah; Bustam, M. Azmi.
Process and Advanced Materials Engineering. ed. / Iqbal Ahmed. Trans Tech Publications Ltd, 2014. p. 188-191 (Applied Mechanics and Materials; Vol. 625).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Modelling of CO2 loading in DEA by using peak ratio of Raman spectroscopy

AU - Shahid, M. Z.

AU - Maulud, Abdulhalim Shah

AU - Bustam, M. Azmi

PY - 2014

Y1 - 2014

N2 - Carbon dioxide (CO2) capturing has been an important issue for decades. Alkanoamines, such as diethanolamine (DEA) have been widely used for CO2 separation by absorption process. During this process, CO2 loading measurement is an imperative action for a proper process control. Currently used methods are titration based which requires a long processing time. In this work Raman spectroscopy is used to model and predict the CO2 loading in wide range (0-0.97 CO2 mole/amine mole). The models are developed by using Raman peak ratios to minimize the error due to peaks fluctuations. The Raman peak ratio of 1022 cm-1/1461cm-1 has been found as a good fit with the coefficient of determination (R2) of 0.92 and mean squared error (MSE) of 0.00656 CO2 mole2/ amine mole2 in prediction of CO2 loading.

AB - Carbon dioxide (CO2) capturing has been an important issue for decades. Alkanoamines, such as diethanolamine (DEA) have been widely used for CO2 separation by absorption process. During this process, CO2 loading measurement is an imperative action for a proper process control. Currently used methods are titration based which requires a long processing time. In this work Raman spectroscopy is used to model and predict the CO2 loading in wide range (0-0.97 CO2 mole/amine mole). The models are developed by using Raman peak ratios to minimize the error due to peaks fluctuations. The Raman peak ratio of 1022 cm-1/1461cm-1 has been found as a good fit with the coefficient of determination (R2) of 0.92 and mean squared error (MSE) of 0.00656 CO2 mole2/ amine mole2 in prediction of CO2 loading.

KW - CO absorption in alkanolamine

KW - CO loading measurement

KW - Raman spectroscopy

UR - https://www.scopus.com/pages/publications/84914168423

U2 - 10.4028/www.scientific.net/AMM.625.188

DO - 10.4028/www.scientific.net/AMM.625.188

M3 - Conference contribution

AN - SCOPUS:84914168423

T3 - Applied Mechanics and Materials

SP - 188

EP - 191

BT - Process and Advanced Materials Engineering

A2 - Ahmed, Iqbal

PB - Trans Tech Publications Ltd

ER -