Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism

Nur Aimi Jani; Larbi Haddad; Ahmed Saud Abdulhameed; Ali H. Jawad; Zeid A. ALOthman; Zaher Mundher Yaseen

doi:10.1007/s13399-022-03319-x

Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism

Nur Aimi Jani
, Larbi Haddad
, Ahmed Saud Abdulhameed
, Ali H. Jawad^*
, Zeid A. ALOthman
, Zaher Mundher Yaseen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

In this study, a renewable and effective bio-adsorbent was derived from Malaysian durian seeds (DSs) to act as a promising biosorbent for phytoremediation application towards removal of a hazardous cationic dye (crystal violet, CV) from aqueous environments. The physiochemical characteristics of DS were investigated by several analytical methods such as FTIR, TGA-DTG, BET, pH_pzc, and SEM-EDX. Subsequently, a statistical optimization for CV removal by DS was carried out via Box-Behnken design (BBD) and numerical desirability function. In this regard, four operational factors that affect CV adsorption, i.e., DS dosage (0.02–0.1 g), initial pH (4–10), temperature (25–50 °C), and adsorption time (5–25 min) were optimized by BBD and numerical desirability function. Hence, the highest CV removal (93.91%) was recorded under the optimal conditions found through desirability function as follows: DS dosage of 0.081 g, solution pH = 9.9, working temperature = 34.6 °C, and contact time = 24.9 min. Furthermore, ANOVA test indicated the significant parametric interactions towards CV removal (%) can be observed between AB (DS dose vs. initial pH), AD (DS dose vs. time), and BC (initial pH vs. temperature) interactions. The adsorption kinetic process was well described by a pseudo-second-order model. Subsequently, the adsorption equilibrium isotherm was well presented by Freundlich and Temkin isotherm models with maximum adsorption capacity of 158 mg/g. Thus, the thermodynamic functions revealed that the adsorption process was spontaneous and endothermic in nature. The adsorption mechanism of CV on the DS surface can be ascribed to the electrostatic forces, n-π stacking, and H-bonding interactions. Thus, the output of the research work indicates the potential applicability of DS as a renewable and effective biosorbent for the removal of CV from aqueous environments.

Original language	English
Pages (from-to)	12441-12454
Number of pages	14
Journal	Biomass Conversion and Biorefinery
Volume	14
Issue number	11
DOIs	https://doi.org/10.1007/s13399-022-03319-x
State	Published - Jun 2024
Externally published	Yes

Bibliographical note

Publisher Copyright:
© The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 15 Life on Land

Keywords

Adsorption
Biomass
Box-Behnken design
Crystal violet dye
Durian seed

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment

Access to Document

10.1007/s13399-022-03319-x

Cite this

Jani, N. A., Haddad, L., Abdulhameed, A. S., Jawad, A. H., ALOthman, Z. A., & Yaseen, Z. M. (2024). Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism. Biomass Conversion and Biorefinery, 14(11), 12441-12454. https://doi.org/10.1007/s13399-022-03319-x

@article{a23d73a15372497a9541a760362ca3e8,

title = "Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism",

abstract = "In this study, a renewable and effective bio-adsorbent was derived from Malaysian durian seeds (DSs) to act as a promising biosorbent for phytoremediation application towards removal of a hazardous cationic dye (crystal violet, CV) from aqueous environments. The physiochemical characteristics of DS were investigated by several analytical methods such as FTIR, TGA-DTG, BET, pHpzc, and SEM-EDX. Subsequently, a statistical optimization for CV removal by DS was carried out via Box-Behnken design (BBD) and numerical desirability function. In this regard, four operational factors that affect CV adsorption, i.e., DS dosage (0.02–0.1 g), initial pH (4–10), temperature (25–50 °C), and adsorption time (5–25 min) were optimized by BBD and numerical desirability function. Hence, the highest CV removal (93.91\%) was recorded under the optimal conditions found through desirability function as follows: DS dosage of 0.081 g, solution pH = 9.9, working temperature = 34.6 °C, and contact time = 24.9 min. Furthermore, ANOVA test indicated the significant parametric interactions towards CV removal (\%) can be observed between AB (DS dose vs. initial pH), AD (DS dose vs. time), and BC (initial pH vs. temperature) interactions. The adsorption kinetic process was well described by a pseudo-second-order model. Subsequently, the adsorption equilibrium isotherm was well presented by Freundlich and Temkin isotherm models with maximum adsorption capacity of 158 mg/g. Thus, the thermodynamic functions revealed that the adsorption process was spontaneous and endothermic in nature. The adsorption mechanism of CV on the DS surface can be ascribed to the electrostatic forces, n-π stacking, and H-bonding interactions. Thus, the output of the research work indicates the potential applicability of DS as a renewable and effective biosorbent for the removal of CV from aqueous environments.",

keywords = "Adsorption, Biomass, Box-Behnken design, Crystal violet dye, Durian seed",

author = "Jani, \{Nur Aimi\} and Larbi Haddad and Abdulhameed, \{Ahmed Saud\} and Jawad, \{Ali H.\} and ALOthman, \{Zeid A.\} and Yaseen, \{Zaher Mundher\}",

note = "Publisher Copyright: {\textcopyright} The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.",

year = "2024",

month = jun,

doi = "10.1007/s13399-022-03319-x",

language = "English",

volume = "14",

pages = "12441--12454",

journal = "Biomass Conversion and Biorefinery",

issn = "2190-6815",

publisher = "Springer Verlag",

number = "11",

}

Jani, NA, Haddad, L, Abdulhameed, AS, Jawad, AH, ALOthman, ZA & Yaseen, ZM 2024, 'Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism', Biomass Conversion and Biorefinery, vol. 14, no. 11, pp. 12441-12454. https://doi.org/10.1007/s13399-022-03319-x

Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism. / Jani, Nur Aimi; Haddad, Larbi; Abdulhameed, Ahmed Saud et al.
In: Biomass Conversion and Biorefinery, Vol. 14, No. 11, 06.2024, p. 12441-12454.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder

T2 - insight into kinetic, isotherm, thermodynamic, and adsorption mechanism

AU - Jani, Nur Aimi

AU - Haddad, Larbi

AU - Abdulhameed, Ahmed Saud

AU - Jawad, Ali H.

AU - ALOthman, Zeid A.

AU - Yaseen, Zaher Mundher

N1 - Publisher Copyright: © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

PY - 2024/6

Y1 - 2024/6

N2 - In this study, a renewable and effective bio-adsorbent was derived from Malaysian durian seeds (DSs) to act as a promising biosorbent for phytoremediation application towards removal of a hazardous cationic dye (crystal violet, CV) from aqueous environments. The physiochemical characteristics of DS were investigated by several analytical methods such as FTIR, TGA-DTG, BET, pHpzc, and SEM-EDX. Subsequently, a statistical optimization for CV removal by DS was carried out via Box-Behnken design (BBD) and numerical desirability function. In this regard, four operational factors that affect CV adsorption, i.e., DS dosage (0.02–0.1 g), initial pH (4–10), temperature (25–50 °C), and adsorption time (5–25 min) were optimized by BBD and numerical desirability function. Hence, the highest CV removal (93.91%) was recorded under the optimal conditions found through desirability function as follows: DS dosage of 0.081 g, solution pH = 9.9, working temperature = 34.6 °C, and contact time = 24.9 min. Furthermore, ANOVA test indicated the significant parametric interactions towards CV removal (%) can be observed between AB (DS dose vs. initial pH), AD (DS dose vs. time), and BC (initial pH vs. temperature) interactions. The adsorption kinetic process was well described by a pseudo-second-order model. Subsequently, the adsorption equilibrium isotherm was well presented by Freundlich and Temkin isotherm models with maximum adsorption capacity of 158 mg/g. Thus, the thermodynamic functions revealed that the adsorption process was spontaneous and endothermic in nature. The adsorption mechanism of CV on the DS surface can be ascribed to the electrostatic forces, n-π stacking, and H-bonding interactions. Thus, the output of the research work indicates the potential applicability of DS as a renewable and effective biosorbent for the removal of CV from aqueous environments.

AB - In this study, a renewable and effective bio-adsorbent was derived from Malaysian durian seeds (DSs) to act as a promising biosorbent for phytoremediation application towards removal of a hazardous cationic dye (crystal violet, CV) from aqueous environments. The physiochemical characteristics of DS were investigated by several analytical methods such as FTIR, TGA-DTG, BET, pHpzc, and SEM-EDX. Subsequently, a statistical optimization for CV removal by DS was carried out via Box-Behnken design (BBD) and numerical desirability function. In this regard, four operational factors that affect CV adsorption, i.e., DS dosage (0.02–0.1 g), initial pH (4–10), temperature (25–50 °C), and adsorption time (5–25 min) were optimized by BBD and numerical desirability function. Hence, the highest CV removal (93.91%) was recorded under the optimal conditions found through desirability function as follows: DS dosage of 0.081 g, solution pH = 9.9, working temperature = 34.6 °C, and contact time = 24.9 min. Furthermore, ANOVA test indicated the significant parametric interactions towards CV removal (%) can be observed between AB (DS dose vs. initial pH), AD (DS dose vs. time), and BC (initial pH vs. temperature) interactions. The adsorption kinetic process was well described by a pseudo-second-order model. Subsequently, the adsorption equilibrium isotherm was well presented by Freundlich and Temkin isotherm models with maximum adsorption capacity of 158 mg/g. Thus, the thermodynamic functions revealed that the adsorption process was spontaneous and endothermic in nature. The adsorption mechanism of CV on the DS surface can be ascribed to the electrostatic forces, n-π stacking, and H-bonding interactions. Thus, the output of the research work indicates the potential applicability of DS as a renewable and effective biosorbent for the removal of CV from aqueous environments.

KW - Adsorption

KW - Biomass

KW - Box-Behnken design

KW - Crystal violet dye

KW - Durian seed

UR - https://www.scopus.com/pages/publications/85138802313

U2 - 10.1007/s13399-022-03319-x

DO - 10.1007/s13399-022-03319-x

M3 - Article

AN - SCOPUS:85138802313

SN - 2190-6815

VL - 14

SP - 12441

EP - 12454

JO - Biomass Conversion and Biorefinery

JF - Biomass Conversion and Biorefinery

IS - 11

ER -

Modeling and optimization of the adsorptive removal of crystal violet dye by durian (Durio zibethinus) seeds powder: insight into kinetic, isotherm, thermodynamic, and adsorption mechanism

Abstract

Bibliographical note

UN SDGs

Keywords

ASJC Scopus subject areas

Access to Document

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