Microwave radiations effect on electrical and mechanical properties of poly (vinyl alcohol) and PVA/graphene nanocomposites

Solution casting technique was used to prepare electrically conductive nanocomposites. Graphene was used as conductive inclusive in the Poly (vinyl alcohol) matrix. Nanocomposites further irradiated using microwave radiation for different interval of time (5, 10 and 15 min). Different characterization techniques were utilized including SEM, XRD and Raman Spectra to completely understand the properties change in non-irradiated and irradiated sample. Increase in electrical conductivity was observed with the increase in graphene percentage. Sample with 10% graphene inclusion exhibited 3.55 S/cm electrical conductivity with comparison to 0.021 S/cm for 1% graphene composite. Percolation threshold was observed for the sample holding 5% graphene with the electrical conductivity value of 2.17 S/cm. Different empirical models were also used to produce the trends for conductivity of composite at different graphene percentages. It was observed that the Scarisbrick model with the 0.1 geometrical factor (C) affirmed the harmonization in theoretical and experimental values of electrical conductivity. Electromagnetic inference shielding effectiveness was perceived for different composite samples using vector network analyzer (VNA). Observations show the increase in EMI shielding with the increase in graphene percentage. Moreover, both electrical conductivity and Electromagnetic inference shielding effectiveness improved after radiation. Due to agglomeration and bi-layered structure domination, tensile properties of composite films were found to be decreased especially at high graphene.