Microporous polyisocyanurate and its application in heterogeneous catalysis

Yugen Zhang; Siti Nurhanna Riduan; Jackie Y. Ying

doi:10.1002/chem.200801570

Microporous polyisocyanurate and its application in heterogeneous catalysis

Yugen Zhang^*
, Siti Nurhanna Riduan
, Jackie Y. Ying

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

The synthesis and catalytic application of microporous polyisocyanurate (PICU) composed of rigid carbon and nitrogen networks was reported. Porous PICU was synthesized by dissolving 1 mmol of monomer in 5 ml of N,N'- dimethylformamide (DMF) in a pressure flask, and adding 0.02 mmol of SItBu NHC. N₂ adsorption analysis confirm the stability and porosity of PICU and also show an isotherm similar to a microporous material. Fe/PICU prepared by suspending in hot DMF solution of FeCl₂ show excellent selectivity and activity as compared to other Fe catalysts. Transmission electron microscopy (TEM) show that no particles are observed in Fe/PICU catalyst and that highly dispersed nanoparticles of approximately 1 nm are noted. Benzyl alcohol is found to be concentrated in the micropores of PICU around the active Fe sites to further promote the catalytic conversion.

Original language	English
Pages (from-to)	1077-1081
Number of pages	5
Journal	Chemistry - A European Journal
Volume	15
Issue number	5
DOIs	https://doi.org/10.1002/chem.200801570
State	Published - 19 Jan 2009
Externally published	Yes

Keywords

Alcohol oxidation
Heterogeneous catalysis
Microporous polymers
Organocatalysis
Polyisocyanurate

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/chem.200801570

Cite this

@article{f94b3bbe0f384e4481383111d76eefdd,

title = "Microporous polyisocyanurate and its application in heterogeneous catalysis",

abstract = "The synthesis and catalytic application of microporous polyisocyanurate (PICU) composed of rigid carbon and nitrogen networks was reported. Porous PICU was synthesized by dissolving 1 mmol of monomer in 5 ml of N,N'- dimethylformamide (DMF) in a pressure flask, and adding 0.02 mmol of SItBu NHC. N2 adsorption analysis confirm the stability and porosity of PICU and also show an isotherm similar to a microporous material. Fe/PICU prepared by suspending in hot DMF solution of FeCl2 show excellent selectivity and activity as compared to other Fe catalysts. Transmission electron microscopy (TEM) show that no particles are observed in Fe/PICU catalyst and that highly dispersed nanoparticles of approximately 1 nm are noted. Benzyl alcohol is found to be concentrated in the micropores of PICU around the active Fe sites to further promote the catalytic conversion.",

keywords = "Alcohol oxidation, Heterogeneous catalysis, Microporous polymers, Organocatalysis, Polyisocyanurate",

author = "Yugen Zhang and Riduan, \{Siti Nurhanna\} and Ying, \{Jackie Y.\}",

year = "2009",

month = jan,

day = "19",

doi = "10.1002/chem.200801570",

language = "English",

volume = "15",

pages = "1077--1081",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc.",

number = "5",

}

TY - JOUR

T1 - Microporous polyisocyanurate and its application in heterogeneous catalysis

AU - Zhang, Yugen

AU - Riduan, Siti Nurhanna

AU - Ying, Jackie Y.

PY - 2009/1/19

Y1 - 2009/1/19

N2 - The synthesis and catalytic application of microporous polyisocyanurate (PICU) composed of rigid carbon and nitrogen networks was reported. Porous PICU was synthesized by dissolving 1 mmol of monomer in 5 ml of N,N'- dimethylformamide (DMF) in a pressure flask, and adding 0.02 mmol of SItBu NHC. N2 adsorption analysis confirm the stability and porosity of PICU and also show an isotherm similar to a microporous material. Fe/PICU prepared by suspending in hot DMF solution of FeCl2 show excellent selectivity and activity as compared to other Fe catalysts. Transmission electron microscopy (TEM) show that no particles are observed in Fe/PICU catalyst and that highly dispersed nanoparticles of approximately 1 nm are noted. Benzyl alcohol is found to be concentrated in the micropores of PICU around the active Fe sites to further promote the catalytic conversion.

AB - The synthesis and catalytic application of microporous polyisocyanurate (PICU) composed of rigid carbon and nitrogen networks was reported. Porous PICU was synthesized by dissolving 1 mmol of monomer in 5 ml of N,N'- dimethylformamide (DMF) in a pressure flask, and adding 0.02 mmol of SItBu NHC. N2 adsorption analysis confirm the stability and porosity of PICU and also show an isotherm similar to a microporous material. Fe/PICU prepared by suspending in hot DMF solution of FeCl2 show excellent selectivity and activity as compared to other Fe catalysts. Transmission electron microscopy (TEM) show that no particles are observed in Fe/PICU catalyst and that highly dispersed nanoparticles of approximately 1 nm are noted. Benzyl alcohol is found to be concentrated in the micropores of PICU around the active Fe sites to further promote the catalytic conversion.

KW - Alcohol oxidation

KW - Heterogeneous catalysis

KW - Microporous polymers

KW - Organocatalysis

KW - Polyisocyanurate

UR - https://www.scopus.com/pages/publications/58449107330

U2 - 10.1002/chem.200801570

DO - 10.1002/chem.200801570

M3 - Article

C2 - 19097124

AN - SCOPUS:58449107330

SN - 0947-6539

VL - 15

SP - 1077

EP - 1081

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 5

ER -

Microporous polyisocyanurate and its application in heterogeneous catalysis

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this