Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants: Conductometric, dye solubilization, and surface tension studies

Md Sayem Alam; A. Mohammed Siddiq; R. Ragupathy; Asit Baran Mandal

doi:10.1080/01932691.2016.1163719

Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants: Conductometric, dye solubilization, and surface tension studies

Md Sayem Alam^*
, A. Mohammed Siddiq
, R. Ragupathy
, Asit Baran Mandal

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

In the present study, we have investigated the self-association, mixed micellization, and thermodynamic studies of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium bromide (16-6-16)) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB). The critical micelle concentration (CMC) of pure (16-6-16 and CTAB) and mixed (16-6-16+CTAB) surfactants was measured by electrical conductivity, dye solubilization, and surface tension measurements. The surface properties (viz., C₂₀ (the surfactant concentration required to reduce the surface tension by 20 mN/m), Π_CMC (the surface pressure at the CMC), Γ_max (maximum surface excess concentration at the air/water interface), A_min (the minimum area per surfactant molecule at the air/water interface), etc.) of micellar (16-6-16 or CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were evaluated. The thermodynamic parameters of the micellar (16-6-16 and CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were also evaluated.

Original language	English
Pages (from-to)	280-287
Number of pages	8
Journal	Journal of Dispersion Science and Technology
Volume	38
Issue number	2
DOIs	https://doi.org/10.1080/01932691.2016.1163719
State	Published - 1 Feb 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017, Copyright © Taylor & Francis.

Keywords

16-6-16
CTAB
Critical micelle concentration
gemini surfactant
mixed micelles thermodynamics

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Polymers and Plastics

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10.1080/01932691.2016.1163719

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@article{49e9cc28281e4dbbaf9599ae7537d3d5,

title = "Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants: Conductometric, dye solubilization, and surface tension studies",

abstract = "In the present study, we have investigated the self-association, mixed micellization, and thermodynamic studies of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium bromide (16-6-16)) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB). The critical micelle concentration (CMC) of pure (16-6-16 and CTAB) and mixed (16-6-16+CTAB) surfactants was measured by electrical conductivity, dye solubilization, and surface tension measurements. The surface properties (viz., C20 (the surfactant concentration required to reduce the surface tension by 20 mN/m), ΠCMC (the surface pressure at the CMC), Γmax (maximum surface excess concentration at the air/water interface), Amin (the minimum area per surfactant molecule at the air/water interface), etc.) of micellar (16-6-16 or CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were evaluated. The thermodynamic parameters of the micellar (16-6-16 and CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were also evaluated.",

keywords = "16-6-16, CTAB, Critical micelle concentration, gemini surfactant, mixed micelles thermodynamics",

author = "Alam, \{Md Sayem\} and Siddiq, \{A. Mohammed\} and R. Ragupathy and Mandal, \{Asit Baran\}",

note = "Publisher Copyright: {\textcopyright} 2017, Copyright {\textcopyright} Taylor \& Francis.",

year = "2017",

month = feb,

day = "1",

doi = "10.1080/01932691.2016.1163719",

language = "English",

volume = "38",

pages = "280--287",

journal = "Journal of Dispersion Science and Technology",

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Alam, MS, Siddiq, AM, Ragupathy, R & Mandal, AB 2017, 'Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants: Conductometric, dye solubilization, and surface tension studies', Journal of Dispersion Science and Technology, vol. 38, no. 2, pp. 280-287. https://doi.org/10.1080/01932691.2016.1163719

Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants: Conductometric, dye solubilization, and surface tension studies. / Alam, Md Sayem; Siddiq, A. Mohammed; Ragupathy, R. et al.
In: Journal of Dispersion Science and Technology, Vol. 38, No. 2, 01.02.2017, p. 280-287.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants

T2 - Conductometric, dye solubilization, and surface tension studies

AU - Alam, Md Sayem

AU - Siddiq, A. Mohammed

AU - Ragupathy, R.

AU - Mandal, Asit Baran

PY - 2017/2/1

Y1 - 2017/2/1

N2 - In the present study, we have investigated the self-association, mixed micellization, and thermodynamic studies of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium bromide (16-6-16)) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB). The critical micelle concentration (CMC) of pure (16-6-16 and CTAB) and mixed (16-6-16+CTAB) surfactants was measured by electrical conductivity, dye solubilization, and surface tension measurements. The surface properties (viz., C20 (the surfactant concentration required to reduce the surface tension by 20 mN/m), ΠCMC (the surface pressure at the CMC), Γmax (maximum surface excess concentration at the air/water interface), Amin (the minimum area per surfactant molecule at the air/water interface), etc.) of micellar (16-6-16 or CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were evaluated. The thermodynamic parameters of the micellar (16-6-16 and CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were also evaluated.

AB - In the present study, we have investigated the self-association, mixed micellization, and thermodynamic studies of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium bromide (16-6-16)) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB). The critical micelle concentration (CMC) of pure (16-6-16 and CTAB) and mixed (16-6-16+CTAB) surfactants was measured by electrical conductivity, dye solubilization, and surface tension measurements. The surface properties (viz., C20 (the surfactant concentration required to reduce the surface tension by 20 mN/m), ΠCMC (the surface pressure at the CMC), Γmax (maximum surface excess concentration at the air/water interface), Amin (the minimum area per surfactant molecule at the air/water interface), etc.) of micellar (16-6-16 or CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were evaluated. The thermodynamic parameters of the micellar (16-6-16 and CTAB) and mixed micellar (16-6-16+CTAB) surfactant systems were also evaluated.

KW - 16-6-16

KW - CTAB

KW - Critical micelle concentration

KW - gemini surfactant

KW - mixed micelles thermodynamics

UR - https://www.scopus.com/pages/publications/84990997267

U2 - 10.1080/01932691.2016.1163719

DO - 10.1080/01932691.2016.1163719

M3 - Article

AN - SCOPUS:84990997267

SN - 0193-2691

VL - 38

SP - 280

EP - 287

JO - Journal of Dispersion Science and Technology

JF - Journal of Dispersion Science and Technology

IS - 2

ER -

Micellization and mixed micellization of cationic gemini (dimeric) surfactants and cationic conventional (monomeric) surfactants: Conductometric, dye solubilization, and surface tension studies

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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