Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction

Abdul Malik Puthan Peedikakkal; Charlene Shi Yun Peh; Lip Lin Koh; Jagadese J. Vittal

doi:10.1021/ic100853h

Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction

Abdul Malik Puthan Peedikakkal, Charlene Shi Yun Peh, Lip Lin Koh, Jagadese J. Vittal

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

The rctt isomer of tetrapyridylcyclobutane prepared from the solid-state [2 + 2] cycloaddition reaction of [bpeH₂]̇2CF₃CO ₂ [bpe = 1,2-bis(4-pyridyl)ethene] undergoes isomerization reaction to the rtct isomer in 100% yield, and this tetrahedral tetrapyridyl ligand forms two metal-organic frameworks having ptt and pts topology.

Original language	English
Pages (from-to)	6775-6777
Number of pages	3
Journal	Inorganic Chemistry
Volume	49
Issue number	15
DOIs	https://doi.org/10.1021/ic100853h
State	Published - 2 Aug 2010
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction",

abstract = "The rctt isomer of tetrapyridylcyclobutane prepared from the solid-state [2 + 2] cycloaddition reaction of [bpeH2{\.]}2CF3CO 2 [bpe = 1,2-bis(4-pyridyl)ethene] undergoes isomerization reaction to the rtct isomer in 100% yield, and this tetrahedral tetrapyridyl ligand forms two metal-organic frameworks having ptt and pts topology.",

author = "Peedikakkal, {Abdul Malik Puthan} and Peh, {Charlene Shi Yun} and Koh, {Lip Lin} and Vittal, {Jagadese J.}",

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journal = "Inorganic Chemistry",

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T1 - Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction

AU - Peedikakkal, Abdul Malik Puthan

AU - Peh, Charlene Shi Yun

AU - Koh, Lip Lin

AU - Vittal, Jagadese J.

PY - 2010/8/2

Y1 - 2010/8/2

N2 - The rctt isomer of tetrapyridylcyclobutane prepared from the solid-state [2 + 2] cycloaddition reaction of [bpeH2]̇2CF3CO 2 [bpe = 1,2-bis(4-pyridyl)ethene] undergoes isomerization reaction to the rtct isomer in 100% yield, and this tetrahedral tetrapyridyl ligand forms two metal-organic frameworks having ptt and pts topology.

AB - The rctt isomer of tetrapyridylcyclobutane prepared from the solid-state [2 + 2] cycloaddition reaction of [bpeH2]̇2CF3CO 2 [bpe = 1,2-bis(4-pyridyl)ethene] undergoes isomerization reaction to the rtct isomer in 100% yield, and this tetrahedral tetrapyridyl ligand forms two metal-organic frameworks having ptt and pts topology.

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U2 - 10.1021/ic100853h

DO - 10.1021/ic100853h

M3 - Article

AN - SCOPUS:77954983780

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 15

ER -

Metal-organic frameworks containing a tetrapyridylcyclobutane ligand derived from isomerization reaction

Abstract

ASJC Scopus subject areas

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