Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}

Muhammad Altaf; Helen Stoeckli-Evans; Syeda Shahzadi Batool; Anvarhusein A. Isab; Saeed Ahmad; Muhammad Saleem; Shafique Ahmad Awan; Muhammad Ashraf Shaheen

doi:10.1080/00958971003759085

Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ²-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}

Muhammad Altaf
, Helen Stoeckli-Evans
, Syeda Shahzadi Batool
, Anvarhusein A. Isab
, Saeed Ahmad^*
, Muhammad Saleem
, Shafique Ahmad Awan
, Muhammad Ashraf Shaheen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl^-, SCN^-, and CN^-) and [Hg(PDTC)₂] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)₂] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg₂(PDTC)₄] (bis[μ²-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.

Original language	English
Pages (from-to)	1176-1185
Number of pages	10
Journal	Journal of Coordination Chemistry
Volume	63
Issue number	7
DOIs	https://doi.org/10.1080/00958971003759085
State	Published - Apr 2010

Bibliographical note

Funding Information:
Financial support from Pakistan Council for Science and Technology, Islamabad is gratefully acknowledged.

Keywords

Crystal structure
Mercury(II)
Pyrrolidinedithiocarbamate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1080/00958971003759085

Cite this

Altaf, M., Stoeckli-Evans, H., Batool, S. S., Isab, A. A., Ahmad, S., Saleem, M., Awan, S. A., & Shaheen, M. A. (2010). Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ²-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}. Journal of Coordination Chemistry, 63(7), 1176-1185. https://doi.org/10.1080/00958971003759085

@article{a9d552f3ccaf46498a642190cd4c6ca1,

title = "Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis\{[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]\}",

abstract = "Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl-, SCN-, and CN-) and [Hg(PDTC)2] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)2] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg2(PDTC)4] (bis[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.",

keywords = "Crystal structure, Mercury(II), Pyrrolidinedithiocarbamate",

author = "Muhammad Altaf and Helen Stoeckli-Evans and Batool, \{Syeda Shahzadi\} and Isab, \{Anvarhusein A.\} and Saeed Ahmad and Muhammad Saleem and Awan, \{Shafique Ahmad\} and Shaheen, \{Muhammad Ashraf\}",

note = "Funding Information: Financial support from Pakistan Council for Science and Technology, Islamabad is gratefully acknowledged.",

year = "2010",

month = apr,

doi = "10.1080/00958971003759085",

language = "English",

volume = "63",

pages = "1176--1185",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "7",

}

Altaf, M, Stoeckli-Evans, H, Batool, SS, Isab, AA, Ahmad, S, Saleem, M, Awan, SA & Shaheen, MA 2010, 'Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ²-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}', Journal of Coordination Chemistry, vol. 63, no. 7, pp. 1176-1185. https://doi.org/10.1080/00958971003759085

Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ²-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}. / Altaf, Muhammad; Stoeckli-Evans, Helen; Batool, Syeda Shahzadi et al.
In: Journal of Coordination Chemistry, Vol. 63, No. 7, 04.2010, p. 1176-1185.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Mercury(II) complexes of pyrrolidinedithiocarbamate, crystal structure of bis{[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]}

AU - Altaf, Muhammad

AU - Stoeckli-Evans, Helen

AU - Batool, Syeda Shahzadi

AU - Isab, Anvarhusein A.

AU - Ahmad, Saeed

AU - Saleem, Muhammad

AU - Awan, Shafique Ahmad

AU - Shaheen, Muhammad Ashraf

N1 - Funding Information: Financial support from Pakistan Council for Science and Technology, Islamabad is gratefully acknowledged.

PY - 2010/4

Y1 - 2010/4

N2 - Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl-, SCN-, and CN-) and [Hg(PDTC)2] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)2] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg2(PDTC)4] (bis[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.

AB - Mercury(II) complexes of pyrrolidinedithiocarbamate (PDTC) having the general formula [Hg(PDTC)X] (X = Cl-, SCN-, and CN-) and [Hg(PDTC)2] have been prepared and characterized by elemental analysis, IR, and NMR. The crystal structure of [Hg(PDTC)2] has also been determined by X-ray crystallography, showing that the complex is a centrosymmetric dimer, [Hg2(PDTC)4] (bis[μ2-(pyrrolidinedithiocarbamato-S,S′)(pyrrolidinedithiocarbamato-S,S′)mercury(II)]) (1). The solid-state structure of 1 contains two crystallographically equivalent Hg(II) centers in a distorted tetrahedron.

KW - Crystal structure

KW - Mercury(II)

KW - Pyrrolidinedithiocarbamate

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DO - 10.1080/00958971003759085

M3 - Article

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SN - 0095-8972

VL - 63

SP - 1176

EP - 1185

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 7

ER -