Mannich bases derived from melamine, formaldehyde alkanoleamines as novel corrosion inhibitors for mild steel in hydrochloric acid medium

Chandrabhan Verma; M. A. Quraishi; E. E. Ebenso

doi:10.1016/s1452-3981(23)13153-1

Mannich bases derived from melamine, formaldehyde alkanoleamines as novel corrosion inhibitors for mild steel in hydrochloric acid medium

Chandrabhan Verma
, M. A. Quraishi^*
, E. E. Ebenso

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The corrosion inhibition of mild steel using two new Mannich bases namely 2,2',2''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)triethanol (INH-1) and 2,2',2'',2''',2''''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)hexaethanol (INH-2) has been investigated using weight loss and electrochemical methods . The INH-1and INH-2 showed maximum efficiency of 92% and 95% at 25ppm concentration respectively. Potentiodynamic polarization suggests that the inhibitors depict mixed type behavior. The Electrochemical impedance spectroscopy (EIS) measurement shows that inhibitors were adsorbed at mild steel surface and obeyed Langmuir adsorption isotherm. Various thermodynamic parameters were also determined to investigate the mechanism of corrosion inhibition. The results obtained from weight loss and electrochemical methods are in good agreements.

Original language	English
Pages (from-to)	10851-10863
Number of pages	13
Journal	International Journal of Electrochemical Science
Volume	8
Issue number	8
DOIs	https://doi.org/10.1016/s1452-3981(23)13153-1
State	Published - 2013
Externally published	Yes

Keywords

Acid corrosion
EIS
Mild steel
Thermodynamic parameter

ASJC Scopus subject areas

Electrochemistry

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10.1016/s1452-3981(23)13153-1

Cite this

@article{b5aaea8af95d4ec5ae33eddfae2af2c8,

title = "Mannich bases derived from melamine, formaldehyde alkanoleamines as novel corrosion inhibitors for mild steel in hydrochloric acid medium",

abstract = "The corrosion inhibition of mild steel using two new Mannich bases namely 2,2',2''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)triethanol (INH-1) and 2,2',2'',2''',2''''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)hexaethanol (INH-2) has been investigated using weight loss and electrochemical methods . The INH-1and INH-2 showed maximum efficiency of 92\% and 95\% at 25ppm concentration respectively. Potentiodynamic polarization suggests that the inhibitors depict mixed type behavior. The Electrochemical impedance spectroscopy (EIS) measurement shows that inhibitors were adsorbed at mild steel surface and obeyed Langmuir adsorption isotherm. Various thermodynamic parameters were also determined to investigate the mechanism of corrosion inhibition. The results obtained from weight loss and electrochemical methods are in good agreements.",

keywords = "Acid corrosion, EIS, Mild steel, Thermodynamic parameter",

author = "Chandrabhan Verma and Quraishi, \{M. A.\} and Ebenso, \{E. E.\}",

year = "2013",

doi = "10.1016/s1452-3981(23)13153-1",

language = "English",

volume = "8",

pages = "10851--10863",

journal = "International Journal of Electrochemical Science",

issn = "1452-3981",

publisher = "Elsevier B.V.",

number = "8",

}

TY - JOUR

T1 - Mannich bases derived from melamine, formaldehyde alkanoleamines as novel corrosion inhibitors for mild steel in hydrochloric acid medium

AU - Verma, Chandrabhan

AU - Quraishi, M. A.

AU - Ebenso, E. E.

PY - 2013

Y1 - 2013

N2 - The corrosion inhibition of mild steel using two new Mannich bases namely 2,2',2''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)triethanol (INH-1) and 2,2',2'',2''',2''''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)hexaethanol (INH-2) has been investigated using weight loss and electrochemical methods . The INH-1and INH-2 showed maximum efficiency of 92% and 95% at 25ppm concentration respectively. Potentiodynamic polarization suggests that the inhibitors depict mixed type behavior. The Electrochemical impedance spectroscopy (EIS) measurement shows that inhibitors were adsorbed at mild steel surface and obeyed Langmuir adsorption isotherm. Various thermodynamic parameters were also determined to investigate the mechanism of corrosion inhibition. The results obtained from weight loss and electrochemical methods are in good agreements.

AB - The corrosion inhibition of mild steel using two new Mannich bases namely 2,2',2''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)triethanol (INH-1) and 2,2',2'',2''',2''''((((1,3,5-triazine-2,4,6-triyl)tris(azanediyl)tris(Methylene)tris(azanediyl)hexaethanol (INH-2) has been investigated using weight loss and electrochemical methods . The INH-1and INH-2 showed maximum efficiency of 92% and 95% at 25ppm concentration respectively. Potentiodynamic polarization suggests that the inhibitors depict mixed type behavior. The Electrochemical impedance spectroscopy (EIS) measurement shows that inhibitors were adsorbed at mild steel surface and obeyed Langmuir adsorption isotherm. Various thermodynamic parameters were also determined to investigate the mechanism of corrosion inhibition. The results obtained from weight loss and electrochemical methods are in good agreements.

KW - Acid corrosion

KW - EIS

KW - Mild steel

KW - Thermodynamic parameter

UR - https://www.scopus.com/pages/publications/84884676598

U2 - 10.1016/s1452-3981(23)13153-1

DO - 10.1016/s1452-3981(23)13153-1

M3 - Article

AN - SCOPUS:84884676598

SN - 1452-3981

VL - 8

SP - 10851

EP - 10863

JO - International Journal of Electrochemical Science

JF - International Journal of Electrochemical Science

IS - 8

ER -

Mannich bases derived from melamine, formaldehyde alkanoleamines as novel corrosion inhibitors for mild steel in hydrochloric acid medium

Abstract

Keywords

ASJC Scopus subject areas

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