Magnetic susceptibility and specific heat of LiNi1.5P2O7

K. Rissouli; M. Bettach; K. Benkhouja; A. Sadel; M. Zahir; M. Pierrot; A. Derrory; M. Drillon

doi:10.1016/S0151-9107(98)80033-0

Magnetic susceptibility and specific heat of LiNi_1.5P₂O₇

K. Rissouli^*
, M. Bettach
, K. Benkhouja
, A. Sadel
, M. Zahir
, M. Pierrot
, A. Derrory
, M. Drillon

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The structure of the diphosphate LiNi_1.5P₂O₇ solved in our laboratory, shows that the Ni²⁺ ions are located in octahedra, which share a common edge and form trimer chains in a zigzag arrangement parallel to the b axis. The thermal evolution of the reciprocal magnetic susceptibility of LiNi_1.5P₂O₇ shows an antiferromagnetic interactions (Θp = -5.7K). The specific heat presents a sharp maximum at 15K close to that observed in the temperature dependence of χ plot, indicates the existence of tridimensional magnetic transition. A weak maximum, detected towards 18K, can be attributed to a low dimensionality order (ID) owing to the presence of the trimer chains of Ni²⁺ ions.

Original language	English
Pages (from-to)	103-106
Number of pages	4
Journal	Annales de Chimie: Science des Materiaux
Volume	23
Issue number	1-2
DOIs	https://doi.org/10.1016/S0151-9107(98)80033-0
State	Published - 1998
Externally published	Yes

ASJC Scopus subject areas

Materials Chemistry

Access to Document

10.1016/S0151-9107(98)80033-0

Cite this

@article{cade0c633d8741d59d43f240d468b32b,

title = "Magnetic susceptibility and specific heat of LiNi1.5P2O7",

abstract = "The structure of the diphosphate LiNi1.5P2O7 solved in our laboratory, shows that the Ni2+ ions are located in octahedra, which share a common edge and form trimer chains in a zigzag arrangement parallel to the b axis. The thermal evolution of the reciprocal magnetic susceptibility of LiNi1.5P2O7 shows an antiferromagnetic interactions (Θp = -5.7K). The specific heat presents a sharp maximum at 15K close to that observed in the temperature dependence of χ plot, indicates the existence of tridimensional magnetic transition. A weak maximum, detected towards 18K, can be attributed to a low dimensionality order (ID) owing to the presence of the trimer chains of Ni2+ ions.",

author = "K. Rissouli and M. Bettach and K. Benkhouja and A. Sadel and M. Zahir and M. Pierrot and A. Derrory and M. Drillon",

year = "1998",

doi = "10.1016/S0151-9107(98)80033-0",

language = "English",

volume = "23",

pages = "103--106",

journal = "Annales de Chimie: Science des Materiaux",

issn = "0151-9107",

publisher = "International Information and Engineering Technology Association",

number = "1-2",

}

TY - JOUR

T1 - Magnetic susceptibility and specific heat of LiNi1.5P2O7

AU - Rissouli, K.

AU - Bettach, M.

AU - Benkhouja, K.

AU - Sadel, A.

AU - Zahir, M.

AU - Pierrot, M.

AU - Derrory, A.

AU - Drillon, M.

PY - 1998

Y1 - 1998

N2 - The structure of the diphosphate LiNi1.5P2O7 solved in our laboratory, shows that the Ni2+ ions are located in octahedra, which share a common edge and form trimer chains in a zigzag arrangement parallel to the b axis. The thermal evolution of the reciprocal magnetic susceptibility of LiNi1.5P2O7 shows an antiferromagnetic interactions (Θp = -5.7K). The specific heat presents a sharp maximum at 15K close to that observed in the temperature dependence of χ plot, indicates the existence of tridimensional magnetic transition. A weak maximum, detected towards 18K, can be attributed to a low dimensionality order (ID) owing to the presence of the trimer chains of Ni2+ ions.

AB - The structure of the diphosphate LiNi1.5P2O7 solved in our laboratory, shows that the Ni2+ ions are located in octahedra, which share a common edge and form trimer chains in a zigzag arrangement parallel to the b axis. The thermal evolution of the reciprocal magnetic susceptibility of LiNi1.5P2O7 shows an antiferromagnetic interactions (Θp = -5.7K). The specific heat presents a sharp maximum at 15K close to that observed in the temperature dependence of χ plot, indicates the existence of tridimensional magnetic transition. A weak maximum, detected towards 18K, can be attributed to a low dimensionality order (ID) owing to the presence of the trimer chains of Ni2+ ions.

UR - https://www.scopus.com/pages/publications/0039413760

U2 - 10.1016/S0151-9107(98)80033-0

DO - 10.1016/S0151-9107(98)80033-0

M3 - Article

AN - SCOPUS:0039413760

SN - 0151-9107

VL - 23

SP - 103

EP - 106

JO - Annales de Chimie: Science des Materiaux

JF - Annales de Chimie: Science des Materiaux

IS - 1-2