Magnetic properties of Fe ions in a silicate glass and ceramic

A. Mekki

doi:10.1002/1521-396X(200104)184:2<327::AID-PSSA327>3.0.CO;2-O

Magnetic properties of Fe ions in a silicate glass and ceramic

A. Mekki^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A homogeneous glass with composition 0.60SiO₂-0.3Na₂O-0.10Fe₂O₃ was prepared and devitrified to produce a glass ceramic having a single crystalline phase of formula Na₅Fe(SiO₃)₄. The dc magnetic susceptibility measurements performed on the glass and the heat-treated sample have shown that the magnetic exchange interaction is antiferromagnetic and of equal strength in both samples investigated. It was shown that M versus H data at different temperatures do not collapse to a single curve in the M versus H/T representation for both the glass and the heat-treated sample, further indicating an antiferromagnetic interaction in both materials. The M versus H data for the glass sample was fitted with Brillouin function by keeping the total number of magnetic ions constant and varying the proportion of ferrous ions until a best fit was achieved. The [Fe²⁺]/[Fe_total] concentration ratio obtained from the fit is in good agreement with the value obtained from X-ray photoelectron spectroscopy (XPS) performed on the glass sample.

Original language	English
Pages (from-to)	327-333
Number of pages	7
Journal	Physica Status Solidi (A) Applied Research
Volume	184
Issue number	2
DOIs	https://doi.org/10.1002/1521-396X(200104)184:2<327::AID-PSSA327>3.0.CO;2-O
State	Published - 2001

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

Access to Document

10.1002/1521-396X(200104)184:2<327::AID-PSSA327>3.0.CO;2-O

Cite this

@article{eddbacd399ac408dbf44eabbd5d0b71e,

title = "Magnetic properties of Fe ions in a silicate glass and ceramic",

abstract = "A homogeneous glass with composition 0.60SiO2-0.3Na2O-0.10Fe2O3 was prepared and devitrified to produce a glass ceramic having a single crystalline phase of formula Na5Fe(SiO3)4. The dc magnetic susceptibility measurements performed on the glass and the heat-treated sample have shown that the magnetic exchange interaction is antiferromagnetic and of equal strength in both samples investigated. It was shown that M versus H data at different temperatures do not collapse to a single curve in the M versus H/T representation for both the glass and the heat-treated sample, further indicating an antiferromagnetic interaction in both materials. The M versus H data for the glass sample was fitted with Brillouin function by keeping the total number of magnetic ions constant and varying the proportion of ferrous ions until a best fit was achieved. The [Fe2+]/[Fetotal] concentration ratio obtained from the fit is in good agreement with the value obtained from X-ray photoelectron spectroscopy (XPS) performed on the glass sample.",

author = "A. Mekki",

year = "2001",

doi = "10.1002/1521-396X(200104)184:2<327::AID-PSSA327>3.0.CO;2-O",

language = "English",

volume = "184",

pages = "327--333",

journal = "Physica Status Solidi (A) Applied Research",

issn = "0031-8965",

publisher = "Wiley-VCH Verlag",

number = "2",

}

TY - JOUR

T1 - Magnetic properties of Fe ions in a silicate glass and ceramic

AU - Mekki, A.

PY - 2001

Y1 - 2001

N2 - A homogeneous glass with composition 0.60SiO2-0.3Na2O-0.10Fe2O3 was prepared and devitrified to produce a glass ceramic having a single crystalline phase of formula Na5Fe(SiO3)4. The dc magnetic susceptibility measurements performed on the glass and the heat-treated sample have shown that the magnetic exchange interaction is antiferromagnetic and of equal strength in both samples investigated. It was shown that M versus H data at different temperatures do not collapse to a single curve in the M versus H/T representation for both the glass and the heat-treated sample, further indicating an antiferromagnetic interaction in both materials. The M versus H data for the glass sample was fitted with Brillouin function by keeping the total number of magnetic ions constant and varying the proportion of ferrous ions until a best fit was achieved. The [Fe2+]/[Fetotal] concentration ratio obtained from the fit is in good agreement with the value obtained from X-ray photoelectron spectroscopy (XPS) performed on the glass sample.

AB - A homogeneous glass with composition 0.60SiO2-0.3Na2O-0.10Fe2O3 was prepared and devitrified to produce a glass ceramic having a single crystalline phase of formula Na5Fe(SiO3)4. The dc magnetic susceptibility measurements performed on the glass and the heat-treated sample have shown that the magnetic exchange interaction is antiferromagnetic and of equal strength in both samples investigated. It was shown that M versus H data at different temperatures do not collapse to a single curve in the M versus H/T representation for both the glass and the heat-treated sample, further indicating an antiferromagnetic interaction in both materials. The M versus H data for the glass sample was fitted with Brillouin function by keeping the total number of magnetic ions constant and varying the proportion of ferrous ions until a best fit was achieved. The [Fe2+]/[Fetotal] concentration ratio obtained from the fit is in good agreement with the value obtained from X-ray photoelectron spectroscopy (XPS) performed on the glass sample.

UR - https://www.scopus.com/pages/publications/0009486382

U2 - 10.1002/1521-396X(200104)184:2<327::AID-PSSA327>3.0.CO;2-O

DO - 10.1002/1521-396X(200104)184:2<327::AID-PSSA327>3.0.CO;2-O

M3 - Article

AN - SCOPUS:0009486382

SN - 0031-8965

VL - 184

SP - 327

EP - 333

JO - Physica Status Solidi (A) Applied Research

JF - Physica Status Solidi (A) Applied Research

IS - 2

ER -

Magnetic properties of Fe ions in a silicate glass and ceramic

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this