Macrocyclization of transition metal complexes of alpha-furilglyoxime and benzilglyoxime

M. Zamil El-Faer; Aqil Khan; M. Sakhawat Hussain

doi:10.1080/00958978708079809

Macrocyclization of transition metal complexes of alpha-furilglyoxime and benzilglyoxime

M. Zamil El-Faer, Aqil Khan, M. Sakhawat Hussain

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

The a-furil- and benzilglyoximates of nickel(II), palladium(II), platinum(II), cobalt(III), rhodium(III) and rhenium(III) have been prepared in a crystalline state and the corresponding macrocycles obtained by reaction with BF3•OEt2utilizing the metal ion as a template. The planar glyoximates yielded macrocycles whereas the macrocyclization of octahedral complexes could not be accomplished. The reactions and the predicted structures have been compared with known structures.

Original language	English
Pages (from-to)	81-87
Number of pages	7
Journal	Journal of Coordination Chemistry
Volume	16
Issue number	1
DOIs	https://doi.org/10.1080/00958978708079809
State	Published - Jan 1987

Keywords

complexes
glyoximes
group 8
synthesis
template

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Materials Chemistry

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10.1080/00958978708079809

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title = "Macrocyclization of transition metal complexes of alpha-furilglyoxime and benzilglyoxime",

abstract = "The a-furil- and benzilglyoximates of nickel(II), palladium(II), platinum(II), cobalt(III), rhodium(III) and rhenium(III) have been prepared in a crystalline state and the corresponding macrocycles obtained by reaction with BF3•OEt2utilizing the metal ion as a template. The planar glyoximates yielded macrocycles whereas the macrocyclization of octahedral complexes could not be accomplished. The reactions and the predicted structures have been compared with known structures.",

keywords = "complexes, glyoximes, group 8, synthesis, template",

author = "El-Faer, \{M. Zamil\} and Aqil Khan and Hussain, \{M. Sakhawat\}",

year = "1987",

month = jan,

doi = "10.1080/00958978708079809",

language = "English",

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T1 - Macrocyclization of transition metal complexes of alpha-furilglyoxime and benzilglyoxime

AU - El-Faer, M. Zamil

AU - Khan, Aqil

AU - Hussain, M. Sakhawat

PY - 1987/1

Y1 - 1987/1

N2 - The a-furil- and benzilglyoximates of nickel(II), palladium(II), platinum(II), cobalt(III), rhodium(III) and rhenium(III) have been prepared in a crystalline state and the corresponding macrocycles obtained by reaction with BF3•OEt2utilizing the metal ion as a template. The planar glyoximates yielded macrocycles whereas the macrocyclization of octahedral complexes could not be accomplished. The reactions and the predicted structures have been compared with known structures.

AB - The a-furil- and benzilglyoximates of nickel(II), palladium(II), platinum(II), cobalt(III), rhodium(III) and rhenium(III) have been prepared in a crystalline state and the corresponding macrocycles obtained by reaction with BF3•OEt2utilizing the metal ion as a template. The planar glyoximates yielded macrocycles whereas the macrocyclization of octahedral complexes could not be accomplished. The reactions and the predicted structures have been compared with known structures.

KW - complexes

KW - glyoximes

KW - group 8

KW - synthesis

KW - template

UR - https://www.scopus.com/pages/publications/0001939316

U2 - 10.1080/00958978708079809

DO - 10.1080/00958978708079809

M3 - Article

AN - SCOPUS:0001939316

SN - 0095-8972

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EP - 87

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 1

ER -

Macrocyclization of transition metal complexes of alpha-furilglyoxime and benzilglyoxime

Abstract

Keywords

ASJC Scopus subject areas

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