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Liquid-phase aerobic oxidation of benzyl alcohol catalyzed by mechanochemically synthesized manganese oxide

  • Mohammad Ilyas*
  • , Mohsin Siddique
  • , Muhammad Saeed
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Benzyl alcohol oxidation by molecular oxygen using solid manganese oxide as a catalyst and n-heptane as the solvent was studied in the liquid phase. The catalyst was synthesized by a simple mechanochemical process at room temperature and was charac-terized by different physical methods. The catalyst was highly active and 100% selective for benzyl alcohol conversion to benzaldehyde. The solid catalyst can be recovered from the reaction mixture by simple filtration and can be re-used. We found n-heptane to be an excellent solvent for the oxidation reaction, and that the catalyst did not leach into solution.

Original languageEnglish
Pages (from-to)2354-2359
Number of pages6
JournalChinese Science Bulletin
Volume58
Issue number19
DOIs
StatePublished - Jul 2013
Externally publishedYes

Bibliographical note

Funding Information:
The authors thank the Higher Education Commission of Pakistan for financial assistance under the Indigenous PhD Fellowship Program.

Keywords

  • benzaldehyde
  • catalyst selectivity
  • chemical analysis
  • environment
  • n-heptane

ASJC Scopus subject areas

  • General

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