Abstract
The collision-assisted electric-quadrupole transition 4 s 21 S 0→4 s3 d 1 D 2 of calcium at 4575 Å has been observed using the laser-enhanced ionization technique for the first time. A blue satellite band due to the interaction of calcium 4 s3 d 1 D 2 state with argon1 S 0 has also been detected at 4527 Å which is shifted by 48 Å from the isolated atomic calcium line. The line broadening cross-section for the blue satellite has been calculated by measuring its collisional broadening at various argon pressures. Important processes involved in the generation of this blue satellite band are qualitatively discussed.
Original language | English |
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Pages (from-to) | 9-16 |
Number of pages | 8 |
Journal | Il Nuovo Cimento D |
Volume | 17 |
Issue number | 1 |
DOIs | |
State | Published - Jan 1995 |
Keywords
- Effects of molecular interactions on electronic structure
- Electronic excitation and ionization of atoms (including beam-foil excitation and ionization)
- Line shapes
- and shifts
- widths
ASJC Scopus subject areas
- General Physics and Astronomy