Laser ablative structural modification of poly(ethylene-alt-maleic anhydride)

Josef Pola; Jaroslav Kupčik; Sardar M.A. Durani; Ehsan E. Khavaja; Husain M. Masoudi; Zdeněk Bastl; Jan Šubrt

doi:10.1021/cm034262m

Laser ablative structural modification of poly(ethylene-alt-maleic anhydride)

Josef Pola^*, Jaroslav Kupčik, Sardar M.A. Durani, Ehsan E. Khavaja, Husain M. Masoudi, Zdeněk Bastl, Jan Šubrt

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH₂- groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO ₂ and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO₂ ^-) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.

Original language	English
Pages (from-to)	3887-3893
Number of pages	7
Journal	Chemistry of Materials
Volume	15
Issue number	20
DOIs	https://doi.org/10.1021/cm034262m
State	Published - 7 Oct 2003

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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title = "Laser ablative structural modification of poly(ethylene-alt-maleic anhydride)",

abstract = "Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH2- groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO 2 and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO2 -) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.",

author = "Josef Pola and Jaroslav Kup{\v c}ik and Durani, \{Sardar M.A.\} and Khavaja, \{Ehsan E.\} and Masoudi, \{Husain M.\} and Zden{\v e}k Bastl and Jan {\v S}ubrt",

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doi = "10.1021/cm034262m",

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T1 - Laser ablative structural modification of poly(ethylene-alt-maleic anhydride)

AU - Pola, Josef

AU - Kupčik, Jaroslav

AU - Durani, Sardar M.A.

AU - Khavaja, Ehsan E.

AU - Masoudi, Husain M.

AU - Bastl, Zdeněk

AU - Šubrt, Jan

PY - 2003/10/7

Y1 - 2003/10/7

N2 - Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH2- groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO 2 and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO2 -) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.

AB - Pulsed IR laser ablation of poly(ethylene-alt-maleic anhydride) results in the deposition of polymeric films possessing the same ratio of anhydride and -CH2- groups and represents a very rare example of laser ablative deposition of polymeric films that are structurally identical to the ablated polymer. This process differs from the conventional thermolysis of poly(ethylene-alt-maleic anhydride) that is controlled by expulsion of CO 2 and CO and yields a nonpolar polymeric residue. The IR laser ablation of poly(ethylene-alt-maleic anhydride) in sodium metasilicate affords deposition of polymeric films containing carboxylate (-CO2 -) groups. This process is the first example of reactive ablation in which the deposited polymeric film incorporates constituents of two different species exposed to laser radiation.

UR - https://www.scopus.com/pages/publications/0141640902

U2 - 10.1021/cm034262m

DO - 10.1021/cm034262m

M3 - Article

AN - SCOPUS:0141640902

SN - 0897-4756

VL - 15

SP - 3887

EP - 3893

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 20

ER -

Laser ablative structural modification of poly(ethylene-alt-maleic anhydride)

Abstract

ASJC Scopus subject areas

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