Large electromechanical strain response in BiFeO3–BaTiO3-based ceramics at elevated temperature

Salman Ali Khan; Tauseef Ahmed; Muhammad Habib; Fazli Akram; Jihee Bae; Tae Kwon Song; Dong Hwan Lim; Soon Jong Jeong; Myong Ho Kim; Soonil Lee

doi:10.1016/j.jpcs.2021.110133

Large electromechanical strain response in BiFeO₃–BaTiO₃-based ceramics at elevated temperature

Salman Ali Khan
, Tauseef Ahmed
, Muhammad Habib
, Fazli Akram
, Jihee Bae
, Tae Kwon Song
, Dong Hwan Lim
, Soon Jong Jeong
, Myong Ho Kim^*
, Soonil Lee^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

An approach of composition modification in (Bi,Na,Ba,Sr)(Ti,Nb,Zr)O₃ (BNSTNZ)–modified 0.65Bi_1.05FeO₃–0.35BaTiO₃ (BF35BT) piezoelectric materials was investigated. Introducing BNSTNZ into BF35BT ceramics led from the normal-ferroelectric to relaxor-ferroelectric- phase. At the optimum composition, large dynamic piezoelectric coefficient (d₃₃*) of 583 pm/V under the applied field of 5 kV/mm and relatively high static piezoelectric coefficient (d₃₃) of 135 pC/N with high maximum temperature (T_m ≤ 400 °C) were obtained. The unipolar strain and d₃₃* of BNSTNZ into BF35BT ceramics with x = 0.005 increased up to 0.251% and 718 pm/V at 90 °C. The remarkably enhanced field-induced strain response of BF35BT-based compositions is believed to be attributed to the optimum grain size, high tetragonality and the ferroelectric-relaxor phase coexistence. It is noted that this composition can be a favorable lead-free candidate for high-temperature piezoelectric applications.

Original language	English
Article number	110133
Journal	Journal of Physics and Chemistry of Solids
Volume	156
DOIs	https://doi.org/10.1016/j.jpcs.2021.110133
State	Published - Sep 2021
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 Elsevier Ltd

Keywords

Electromechanical
Ferroelectric
Lead-free
Piezoelectric
Temperature dependence

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1016/j.jpcs.2021.110133

Cite this

@article{c8e87e1c4d4c4c5d9f0b4aa1a7ef4453,

title = "Large electromechanical strain response in BiFeO3–BaTiO3-based ceramics at elevated temperature",

abstract = "An approach of composition modification in (Bi,Na,Ba,Sr)(Ti,Nb,Zr)O3 (BNSTNZ)–modified 0.65Bi1.05FeO3–0.35BaTiO3 (BF35BT) piezoelectric materials was investigated. Introducing BNSTNZ into BF35BT ceramics led from the normal-ferroelectric to relaxor-ferroelectric- phase. At the optimum composition, large dynamic piezoelectric coefficient (d33*) of 583 pm/V under the applied field of 5 kV/mm and relatively high static piezoelectric coefficient (d33) of 135 pC/N with high maximum temperature (Tm ≤ 400 °C) were obtained. The unipolar strain and d33* of BNSTNZ into BF35BT ceramics with x = 0.005 increased up to 0.251\% and 718 pm/V at 90 °C. The remarkably enhanced field-induced strain response of BF35BT-based compositions is believed to be attributed to the optimum grain size, high tetragonality and the ferroelectric-relaxor phase coexistence. It is noted that this composition can be a favorable lead-free candidate for high-temperature piezoelectric applications.",

keywords = "Electromechanical, Ferroelectric, Lead-free, Piezoelectric, Temperature dependence",

author = "Khan, \{Salman Ali\} and Tauseef Ahmed and Muhammad Habib and Fazli Akram and Jihee Bae and Song, \{Tae Kwon\} and Lim, \{Dong Hwan\} and Jeong, \{Soon Jong\} and Kim, \{Myong Ho\} and Soonil Lee",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",

year = "2021",

month = sep,

doi = "10.1016/j.jpcs.2021.110133",

language = "English",

volume = "156",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Large electromechanical strain response in BiFeO3–BaTiO3-based ceramics at elevated temperature

AU - Khan, Salman Ali

AU - Ahmed, Tauseef

AU - Habib, Muhammad

AU - Akram, Fazli

AU - Bae, Jihee

AU - Song, Tae Kwon

AU - Lim, Dong Hwan

AU - Jeong, Soon Jong

AU - Kim, Myong Ho

AU - Lee, Soonil

PY - 2021/9

Y1 - 2021/9

N2 - An approach of composition modification in (Bi,Na,Ba,Sr)(Ti,Nb,Zr)O3 (BNSTNZ)–modified 0.65Bi1.05FeO3–0.35BaTiO3 (BF35BT) piezoelectric materials was investigated. Introducing BNSTNZ into BF35BT ceramics led from the normal-ferroelectric to relaxor-ferroelectric- phase. At the optimum composition, large dynamic piezoelectric coefficient (d33*) of 583 pm/V under the applied field of 5 kV/mm and relatively high static piezoelectric coefficient (d33) of 135 pC/N with high maximum temperature (Tm ≤ 400 °C) were obtained. The unipolar strain and d33* of BNSTNZ into BF35BT ceramics with x = 0.005 increased up to 0.251% and 718 pm/V at 90 °C. The remarkably enhanced field-induced strain response of BF35BT-based compositions is believed to be attributed to the optimum grain size, high tetragonality and the ferroelectric-relaxor phase coexistence. It is noted that this composition can be a favorable lead-free candidate for high-temperature piezoelectric applications.

AB - An approach of composition modification in (Bi,Na,Ba,Sr)(Ti,Nb,Zr)O3 (BNSTNZ)–modified 0.65Bi1.05FeO3–0.35BaTiO3 (BF35BT) piezoelectric materials was investigated. Introducing BNSTNZ into BF35BT ceramics led from the normal-ferroelectric to relaxor-ferroelectric- phase. At the optimum composition, large dynamic piezoelectric coefficient (d33*) of 583 pm/V under the applied field of 5 kV/mm and relatively high static piezoelectric coefficient (d33) of 135 pC/N with high maximum temperature (Tm ≤ 400 °C) were obtained. The unipolar strain and d33* of BNSTNZ into BF35BT ceramics with x = 0.005 increased up to 0.251% and 718 pm/V at 90 °C. The remarkably enhanced field-induced strain response of BF35BT-based compositions is believed to be attributed to the optimum grain size, high tetragonality and the ferroelectric-relaxor phase coexistence. It is noted that this composition can be a favorable lead-free candidate for high-temperature piezoelectric applications.

KW - Electromechanical

KW - Ferroelectric

KW - Lead-free

KW - Piezoelectric

KW - Temperature dependence

UR - https://www.scopus.com/pages/publications/85105603609

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DO - 10.1016/j.jpcs.2021.110133

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