Abstract
Secondary and tertiary allylic alcohols react with carbon monoxide in the presence of catalytic quantities of bis(dibenzylideneacetone)palladium(0) and 1,4-bis(diphenylphosphino)butane affording lactones in 45-92% isolated yields. α,β-Unsaturated acids are formed by isomerization and carbonylation of primary allylic alcohols. 2-(5H)-Furanones were isolated in yields of 60-80% when alkynols were employed as substrates for the cyclo-carbonylation process.
| Original language | English |
|---|---|
| Pages (from-to) | 5357-5360 |
| Number of pages | 4 |
| Journal | Journal of Organic Chemistry |
| Volume | 56 |
| Issue number | 18 |
| DOIs | |
| State | Published - 1 Aug 1991 |
| Externally published | Yes |
ASJC Scopus subject areas
- Organic Chemistry
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