Laboratory techniques to measure thermodynamic asphaltene instability

Asphaltenes are the n-pentane or n-heptane insoluble fractions of crude oil that remain in solution under reservoir temperature and pressure conditions. They are destabilized and start to precipitate when the pressure, temperature, and/or composition changes occur during primary production. The precipitated asphaltene particles will then grow in size, and may start to deposit onto the production string and/or flowlines, causing operational problems. In this paper, our emphasis is to identify the first pressure and/or temperature conditions at which the asphaltene will start to precipitate for two reservoir oils. Four different laboratory techniques were independently used to define the onset of the asphaltene precipitation envelope. These methods are: 1) gravimetric; 2) acoustic resonance; 3) light scattering; and 4) filtration. The gravimetric method was found to be precise, and within the accuracy of the analytical methods. However, the method was time consuming. The acoustic resonance technique (ART) was fast and less subjective, but it did not define the lower asphaltene boundary. The interpretation of the onset pressure from the near-infrared (NIR) light-scattering technique (LST) was subjective to a degree. However, the NIR response defined the upper and lower boundaries of the asphaltene envelope and the bubblepoint pressure, as did the gravimetric technique. In a manner similar to those of the gravimetric technique and LST, the filtration technique can also define the upper and lower asphaltene phase boundaries, in addition to the bubble-point pressure. The filtration technique is fact compared to the gravimetric technique, but takes more time than the ART and LST methods.