Kinetic study of combined steam and CO2 reforming of methane over Ni-Sr/MgO-ZrO2 catalyst

Salam Farooqi Ahmad; Abdullah Bawadi; Marias Frederic; Yap Yi Tong Amanda; Ishtiaq Umair

doi:10.21741/9781644902516-46

Kinetic study of combined steam and CO₂ reforming of methane over Ni-Sr/MgO-ZrO₂ catalyst

Salam Farooqi Ahmad^*
, Abdullah Bawadi
, Marias Frederic
, Yap Yi Tong Amanda
, Ishtiaq Umair

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Combined steam and CO₂ reforming of methane (CSCRM) has gained increasing attention as a potential solution to mitigate global warming and addressing the demand for alternative energy resources. In this study, the reaction kinetics of CSCRM over high-performance Ni-Sr/MgO-ZrO₂ bimetallic catalyst is investigated in a fixed bed reactor. The rate of reaction was analyzed at a temperatures ranging from 700-800℃ and reactant partial pressures of CH4, CO₂ and H₂O ranging from 5-50 kPa. The apparent activation energies for CH₄ and CO₂ consumption were found to be 20.94 kJ/mol and 27.53 kJ/mol respectively. The experimental results obtained were then fitted with a Power Law kinetic model and showed good agreement with R2 values of 0.86-0.91.

Original language	English
Title of host publication	Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022
Editors	Yeong Yin Fong, Lam Man Kee, Norwahyu Jusoh, Chong Yang Chuah
Publisher	Association of American Publishers
Pages	407-415
Number of pages	9
ISBN (Print)	9781644902509
DOIs	https://doi.org/10.21741/9781644902516-46
State	Published - 2023
Externally published	Yes
Event	International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022 - Kuching, Malaysia Duration: 1 Dec 2022 → 2 Dec 2022

Publication series

Name	Materials Research Proceedings
Volume	29
ISSN (Print)	2474-3941
ISSN (Electronic)	2474-395X

Conference

Conference	International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022
Country/Territory	Malaysia
City	Kuching
Period	1/12/22 → 2/12/22

Bibliographical note

Publisher Copyright:
© 2023, Association of American Publishers. All rights reserved.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 13 Climate Action

Keywords

Activation Energy
Bimetallic Catalyst
CSCRM
Power Law
Reaction Kinetics

ASJC Scopus subject areas

General Materials Science

Access to Document

10.21741/9781644902516-46

Cite this

Ahmad, S. F., Bawadi, A., Frederic, M., Amanda, Y. Y. T., & Umair, I. (2023). Kinetic study of combined steam and CO₂ reforming of methane over Ni-Sr/MgO-ZrO₂ catalyst. In Y. Yin Fong, L. Man Kee, N. Jusoh, & C. Y. Chuah (Eds.), Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022 (pp. 407-415). (Materials Research Proceedings; Vol. 29). Association of American Publishers. https://doi.org/10.21741/9781644902516-46

Ahmad, Salam Farooqi ; Bawadi, Abdullah ; Frederic, Marias et al. / Kinetic study of combined steam and CO₂ reforming of methane over Ni-Sr/MgO-ZrO₂ catalyst. Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022. editor / Yeong Yin Fong ; Lam Man Kee ; Norwahyu Jusoh ; Chong Yang Chuah. Association of American Publishers, 2023. pp. 407-415 (Materials Research Proceedings).

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title = "Kinetic study of combined steam and CO2 reforming of methane over Ni-Sr/MgO-ZrO2 catalyst",

abstract = "Combined steam and CO2 reforming of methane (CSCRM) has gained increasing attention as a potential solution to mitigate global warming and addressing the demand for alternative energy resources. In this study, the reaction kinetics of CSCRM over high-performance Ni-Sr/MgO-ZrO2 bimetallic catalyst is investigated in a fixed bed reactor. The rate of reaction was analyzed at a temperatures ranging from 700-800℃ and reactant partial pressures of CH4, CO2 and H2O ranging from 5-50 kPa. The apparent activation energies for CH4 and CO2 consumption were found to be 20.94 kJ/mol and 27.53 kJ/mol respectively. The experimental results obtained were then fitted with a Power Law kinetic model and showed good agreement with R2 values of 0.86-0.91.",

keywords = "Activation Energy, Bimetallic Catalyst, CSCRM, Power Law, Reaction Kinetics",

author = "Ahmad, \{Salam Farooqi\} and Abdullah Bawadi and Marias Frederic and Amanda, \{Yap Yi Tong\} and Ishtiaq Umair",

note = "Publisher Copyright: {\textcopyright} 2023, Association of American Publishers. All rights reserved.; International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022 ; Conference date: 01-12-2022 Through 02-12-2022",

year = "2023",

doi = "10.21741/9781644902516-46",

language = "English",

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Ahmad, SF, Bawadi, A, Frederic, M, Amanda, YYT & Umair, I 2023, Kinetic study of combined steam and CO₂ reforming of methane over Ni-Sr/MgO-ZrO₂ catalyst. in Y Yin Fong, L Man Kee, N Jusoh & CY Chuah (eds), Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022. Materials Research Proceedings, vol. 29, Association of American Publishers, pp. 407-415, International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022, Kuching, Malaysia, 1/12/22. https://doi.org/10.21741/9781644902516-46

Kinetic study of combined steam and CO₂ reforming of methane over Ni-Sr/MgO-ZrO₂ catalyst. / Ahmad, Salam Farooqi; Bawadi, Abdullah; Frederic, Marias et al.
Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022. ed. / Yeong Yin Fong; Lam Man Kee; Norwahyu Jusoh; Chong Yang Chuah. Association of American Publishers, 2023. p. 407-415 (Materials Research Proceedings; Vol. 29).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Kinetic study of combined steam and CO2 reforming of methane over Ni-Sr/MgO-ZrO2 catalyst

AU - Ahmad, Salam Farooqi

AU - Bawadi, Abdullah

AU - Frederic, Marias

AU - Amanda, Yap Yi Tong

AU - Umair, Ishtiaq

PY - 2023

Y1 - 2023

N2 - Combined steam and CO2 reforming of methane (CSCRM) has gained increasing attention as a potential solution to mitigate global warming and addressing the demand for alternative energy resources. In this study, the reaction kinetics of CSCRM over high-performance Ni-Sr/MgO-ZrO2 bimetallic catalyst is investigated in a fixed bed reactor. The rate of reaction was analyzed at a temperatures ranging from 700-800℃ and reactant partial pressures of CH4, CO2 and H2O ranging from 5-50 kPa. The apparent activation energies for CH4 and CO2 consumption were found to be 20.94 kJ/mol and 27.53 kJ/mol respectively. The experimental results obtained were then fitted with a Power Law kinetic model and showed good agreement with R2 values of 0.86-0.91.

AB - Combined steam and CO2 reforming of methane (CSCRM) has gained increasing attention as a potential solution to mitigate global warming and addressing the demand for alternative energy resources. In this study, the reaction kinetics of CSCRM over high-performance Ni-Sr/MgO-ZrO2 bimetallic catalyst is investigated in a fixed bed reactor. The rate of reaction was analyzed at a temperatures ranging from 700-800℃ and reactant partial pressures of CH4, CO2 and H2O ranging from 5-50 kPa. The apparent activation energies for CH4 and CO2 consumption were found to be 20.94 kJ/mol and 27.53 kJ/mol respectively. The experimental results obtained were then fitted with a Power Law kinetic model and showed good agreement with R2 values of 0.86-0.91.

KW - Activation Energy

KW - Bimetallic Catalyst

KW - CSCRM

KW - Power Law

KW - Reaction Kinetics

UR - https://www.scopus.com/pages/publications/85161642069

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DO - 10.21741/9781644902516-46

M3 - Conference contribution

AN - SCOPUS:85161642069

SN - 9781644902509

T3 - Materials Research Proceedings

SP - 407

EP - 415

BT - Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022

A2 - Yin Fong, Yeong

A2 - Man Kee, Lam

A2 - Jusoh, Norwahyu

A2 - Chuah, Chong Yang

PB - Association of American Publishers

T2 - International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022

Y2 - 1 December 2022 through 2 December 2022

ER -

Ahmad SF, Bawadi A, Frederic M, Amanda YYT, Umair I. Kinetic study of combined steam and CO₂ reforming of methane over Ni-Sr/MgO-ZrO₂ catalyst. In Yin Fong Y, Man Kee L, Jusoh N, Chuah CY, editors, Sustainable Processes and Clean Energy Transition- International Conference on Sustainable Processes and Clean Energy Transition, ICSuPCET 2022. Association of American Publishers. 2023. p. 407-415. (Materials Research Proceedings). doi: 10.21741/9781644902516-46