Kinetic Investigation for Chemical Depolymerization of Post-Consumer PET Waste Using Sodium Ethoxide

Reaction kinetics provides significant insights into the reaction rate and mechanism to control a chemical reaction. In the present work, the detailed kinetics of glycolytic depolymerization of post-consumer polyethylene terephthalate (PET) waste in the presence of sodium ethoxide (EtONa) was investigated. The glycolysis experiments were conducted in a batch reactor over a temperature range of 160 to 197 °C. The confirmation of the product, the bis(2-hydroxyethyl)terephthalate monomer, was carried out using nuclear magnetic resonance spectroscopy, high-performance liquid chromatography, differential scanning calorimetry, and X-ray diffraction techniques. Investigations on the influence of particle size and temperature showed that conversion increased with a decrease in particle size and increasing temperature. Equilibrium conversions were found at different temperatures, and a van ’t Hoff plot was used to confirm that the depolymerization reaction is endothermic. Gibbs’ free energy was used to calculate the ceiling temperature (T_C = 156 °C). Three kinetic models were tested for their applicability. It was found that the EtONa-catalyzed glycolysis of PET follows a first-order reversible reaction kinetic model at higher temperatures (170-197 °C). However, a heterogeneous shrinking core mechanism was applicable in a lower temperature range (160-170 °C). The kinetic evaluation revealed that the PET glycolysis reaction consists of heterogeneous and homogeneous mechanisms depending upon the depolymerization stages at various temperatures.