Investigation of vanadium-sodium silicate glasses using XANES spectroscopy

M. Faiz; A. Mekki; B. S. Mun; Z. Hussain

doi:10.1016/j.elspec.2006.11.006

Investigation of vanadium-sodium silicate glasses using XANES spectroscopy

M. Faiz^*, A. Mekki, B. S. Mun, Z. Hussain

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

X-ray absorption near edge structure spectroscopy has been used to investigate the electronic and atomic structure of (V₂O₅)_x(Na₂O)_0.30(SiO₂)_0.70-x (x < 0.1) glasses obtained by melt-quench technique. The results show no sign of metallic clustering of V atoms, but mixed oxidation states (+4 and +5) of V and strong V3d-O2p hybridization in the glasses. Detailed analysis has revealed that the glass samples contain about 15% V⁴⁺ and 85% V⁵⁺ and the ligand-field splitting is about 1.6 eV.

Original language	English
Pages (from-to)	60-62
Number of pages	3
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	154
Issue number	3
DOIs	https://doi.org/10.1016/j.elspec.2006.11.006
State	Published - Feb 2007

Bibliographical note

Funding Information:
The Advanced Light Source is supported by the Office of Basic Energy Sciences of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Faiz and Mekki would like to thank King Fahd University of Petroleum and Minerals for its support.

Keywords

O K edge
V L edges
Vanadium-sodium silicate glasses
XANES

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Radiation
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

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10.1016/j.elspec.2006.11.006

Cite this

@article{0620d36e6ab447c6a1deac401b2f30a5,

title = "Investigation of vanadium-sodium silicate glasses using XANES spectroscopy",

abstract = "X-ray absorption near edge structure spectroscopy has been used to investigate the electronic and atomic structure of (V2O5)x(Na2O)0.30(SiO2)0.70-x (x < 0.1) glasses obtained by melt-quench technique. The results show no sign of metallic clustering of V atoms, but mixed oxidation states (+4 and +5) of V and strong V3d-O2p hybridization in the glasses. Detailed analysis has revealed that the glass samples contain about 15\% V4+ and 85\% V5+ and the ligand-field splitting is about 1.6 eV.",

keywords = "O K edge, V L edges, Vanadium-sodium silicate glasses, XANES",

author = "M. Faiz and A. Mekki and Mun, \{B. S.\} and Z. Hussain",

note = "Funding Information: The Advanced Light Source is supported by the Office of Basic Energy Sciences of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Faiz and Mekki would like to thank King Fahd University of Petroleum and Minerals for its support.",

year = "2007",

month = feb,

doi = "10.1016/j.elspec.2006.11.006",

language = "English",

volume = "154",

pages = "60--62",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

issn = "0368-2048",

publisher = "Elsevier B.V.",

number = "3",

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TY - JOUR

T1 - Investigation of vanadium-sodium silicate glasses using XANES spectroscopy

AU - Faiz, M.

AU - Mekki, A.

AU - Mun, B. S.

AU - Hussain, Z.

N1 - Funding Information: The Advanced Light Source is supported by the Office of Basic Energy Sciences of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Faiz and Mekki would like to thank King Fahd University of Petroleum and Minerals for its support.

PY - 2007/2

Y1 - 2007/2

N2 - X-ray absorption near edge structure spectroscopy has been used to investigate the electronic and atomic structure of (V2O5)x(Na2O)0.30(SiO2)0.70-x (x < 0.1) glasses obtained by melt-quench technique. The results show no sign of metallic clustering of V atoms, but mixed oxidation states (+4 and +5) of V and strong V3d-O2p hybridization in the glasses. Detailed analysis has revealed that the glass samples contain about 15% V4+ and 85% V5+ and the ligand-field splitting is about 1.6 eV.

AB - X-ray absorption near edge structure spectroscopy has been used to investigate the electronic and atomic structure of (V2O5)x(Na2O)0.30(SiO2)0.70-x (x < 0.1) glasses obtained by melt-quench technique. The results show no sign of metallic clustering of V atoms, but mixed oxidation states (+4 and +5) of V and strong V3d-O2p hybridization in the glasses. Detailed analysis has revealed that the glass samples contain about 15% V4+ and 85% V5+ and the ligand-field splitting is about 1.6 eV.

KW - O K edge

KW - V L edges

KW - Vanadium-sodium silicate glasses

KW - XANES

UR - https://www.scopus.com/pages/publications/33847060803

U2 - 10.1016/j.elspec.2006.11.006

DO - 10.1016/j.elspec.2006.11.006

M3 - Article

AN - SCOPUS:33847060803

SN - 0368-2048

VL - 154

SP - 60

EP - 62

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

IS - 3

ER -

Investigation of vanadium-sodium silicate glasses using XANES spectroscopy

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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