Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution

Anvarhusein A. Isab; Abdul Rahman A. Al-Arfaj

doi:10.1007/BF01024068

Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution

Anvarhusein A. Isab^*
, Abdul Rahman A. Al-Arfaj

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The interaction of Pd^II with DL-selenamethionine (SeMet) in acidic aqueous solution was investigated. SeMet was found to act as a bidentate ligand, forming a stable complex with Pd^II. Binding of the metal ion to the selenoether group creates a new chiral centre, which generates two sets of¹H and¹³C n.m.r. methyl resonances for the two diastereoisomers. The²J values for (⁷⁷Se-Me) decreased upon complex formation.

Original language	English
Pages (from-to)	304-307
Number of pages	4
Journal	Transition Metal Chemistry
Volume	16
Issue number	3
DOIs	https://doi.org/10.1007/BF01024068
State	Published - Jun 1991

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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title = "Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution",

abstract = "The interaction of PdII with DL-selenamethionine (SeMet) in acidic aqueous solution was investigated. SeMet was found to act as a bidentate ligand, forming a stable complex with PdII. Binding of the metal ion to the selenoether group creates a new chiral centre, which generates two sets of1H and13C n.m.r. methyl resonances for the two diastereoisomers. The2J values for (77Se-Me) decreased upon complex formation.",

author = "Isab, \{Anvarhusein A.\} and Al-Arfaj, \{Abdul Rahman A.\}",

year = "1991",

month = jun,

doi = "10.1007/BF01024068",

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journal = "Transition Metal Chemistry",

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AU - Isab, Anvarhusein A.

AU - Al-Arfaj, Abdul Rahman A.

PY - 1991/6

Y1 - 1991/6

N2 - The interaction of PdII with DL-selenamethionine (SeMet) in acidic aqueous solution was investigated. SeMet was found to act as a bidentate ligand, forming a stable complex with PdII. Binding of the metal ion to the selenoether group creates a new chiral centre, which generates two sets of1H and13C n.m.r. methyl resonances for the two diastereoisomers. The2J values for (77Se-Me) decreased upon complex formation.

AB - The interaction of PdII with DL-selenamethionine (SeMet) in acidic aqueous solution was investigated. SeMet was found to act as a bidentate ligand, forming a stable complex with PdII. Binding of the metal ion to the selenoether group creates a new chiral centre, which generates two sets of1H and13C n.m.r. methyl resonances for the two diastereoisomers. The2J values for (77Se-Me) decreased upon complex formation.

UR - https://www.scopus.com/pages/publications/0010937451

U2 - 10.1007/BF01024068

DO - 10.1007/BF01024068

M3 - Article

AN - SCOPUS:0010937451

SN - 0340-4285

VL - 16

SP - 304

EP - 307

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 3

ER -

Interaction of palladium(II) with DL-selenamethionine in acidic aqueous solution

Abstract

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