Influence of iron microstructure on the performance of polyacrylic acid as corrosion inhibitor in sulfuric acid solution

S. A. Umoren; Y. Li; F. H. Wang

doi:10.1016/j.corsci.2011.01.052

Influence of iron microstructure on the performance of polyacrylic acid as corrosion inhibitor in sulfuric acid solution

S. A. Umoren^*
, Y. Li
, F. H. Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

The corrosion inhibition behavior of bulk nanocrystalline ingot iron (BNII) fabricated from coarse polycrystalline ingot iron (CPII) by severe rolling technique by polyacrylic acid (PAA) was studied in 0.1M H₂SO₄ using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that PAA inhibited the acid induced corrosion of both iron specimens, with greater effect noted for BNII. The corrosion inhibiting effect was influenced by the microstructure of the iron samples. Synergistic inhibition effect was observed on addition of iodide ions to PAA in case of CPII while for BNII inhibition efficiency marginally increased.

Original language	English
Pages (from-to)	1778-1785
Number of pages	8
Journal	Corrosion Science
Volume	53
Issue number	5
DOIs	https://doi.org/10.1016/j.corsci.2011.01.052
State	Published - May 2011
Externally published	Yes

Bibliographical note

Funding Information:
S.A Umoren is grateful to the Chinese Academy of Sciences (CAS) and Academy of Sciences for the Developing World (TWAS) for the CAS-TWAS Postdoctoral Fellowship.

Keywords

A. Iron
A. Polyacrylic acid
C. Corrosion inhibition
C. Microstructures
C. Nanocrystallization

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
General Materials Science

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10.1016/j.corsci.2011.01.052

Cite this

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title = "Influence of iron microstructure on the performance of polyacrylic acid as corrosion inhibitor in sulfuric acid solution",

abstract = "The corrosion inhibition behavior of bulk nanocrystalline ingot iron (BNII) fabricated from coarse polycrystalline ingot iron (CPII) by severe rolling technique by polyacrylic acid (PAA) was studied in 0.1M H2SO4 using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that PAA inhibited the acid induced corrosion of both iron specimens, with greater effect noted for BNII. The corrosion inhibiting effect was influenced by the microstructure of the iron samples. Synergistic inhibition effect was observed on addition of iodide ions to PAA in case of CPII while for BNII inhibition efficiency marginally increased.",

keywords = "A. Iron, A. Polyacrylic acid, C. Corrosion inhibition, C. Microstructures, C. Nanocrystallization",

author = "Umoren, \{S. A.\} and Y. Li and Wang, \{F. H.\}",

note = "Funding Information: S.A Umoren is grateful to the Chinese Academy of Sciences (CAS) and Academy of Sciences for the Developing World (TWAS) for the CAS-TWAS Postdoctoral Fellowship.",

year = "2011",

month = may,

doi = "10.1016/j.corsci.2011.01.052",

language = "English",

volume = "53",

pages = "1778--1785",

journal = "Corrosion Science",

issn = "0010-938X",

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TY - JOUR

T1 - Influence of iron microstructure on the performance of polyacrylic acid as corrosion inhibitor in sulfuric acid solution

AU - Umoren, S. A.

AU - Li, Y.

AU - Wang, F. H.

N1 - Funding Information: S.A Umoren is grateful to the Chinese Academy of Sciences (CAS) and Academy of Sciences for the Developing World (TWAS) for the CAS-TWAS Postdoctoral Fellowship.

PY - 2011/5

Y1 - 2011/5

N2 - The corrosion inhibition behavior of bulk nanocrystalline ingot iron (BNII) fabricated from coarse polycrystalline ingot iron (CPII) by severe rolling technique by polyacrylic acid (PAA) was studied in 0.1M H2SO4 using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that PAA inhibited the acid induced corrosion of both iron specimens, with greater effect noted for BNII. The corrosion inhibiting effect was influenced by the microstructure of the iron samples. Synergistic inhibition effect was observed on addition of iodide ions to PAA in case of CPII while for BNII inhibition efficiency marginally increased.

AB - The corrosion inhibition behavior of bulk nanocrystalline ingot iron (BNII) fabricated from coarse polycrystalline ingot iron (CPII) by severe rolling technique by polyacrylic acid (PAA) was studied in 0.1M H2SO4 using electrochemical impedance spectroscopy and potentiodynamic polarization techniques. The results indicated that PAA inhibited the acid induced corrosion of both iron specimens, with greater effect noted for BNII. The corrosion inhibiting effect was influenced by the microstructure of the iron samples. Synergistic inhibition effect was observed on addition of iodide ions to PAA in case of CPII while for BNII inhibition efficiency marginally increased.

KW - A. Iron

KW - A. Polyacrylic acid

KW - C. Corrosion inhibition

KW - C. Microstructures

KW - C. Nanocrystallization

UR - https://www.scopus.com/pages/publications/79952898861

U2 - 10.1016/j.corsci.2011.01.052

DO - 10.1016/j.corsci.2011.01.052

M3 - Article

AN - SCOPUS:79952898861

SN - 0010-938X

VL - 53

SP - 1778

EP - 1785

JO - Corrosion Science

JF - Corrosion Science

IS - 5

ER -

Influence of iron microstructure on the performance of polyacrylic acid as corrosion inhibitor in sulfuric acid solution

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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