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Influence of Amphiphilic Plasticizer on Properties of Thermoplastic Starch Films

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Thermoplastic starch powders and films were produced by using different combinations of hydrophilic (malic acid and water) and amphiphilic (isoleucine and butyric acid) plasticizers. Spray drying was used to produce thermoplastic starch powder followed by compression molding for the development of films. In all plasticized formulations, the rate of retrogradation was inhibited until the seventh day. The crystallinity and moisture sensitivity of the freshly prepared films were dependent on amphiphilic plasticizer quantity in formulation. Fourier transform infrared spectroscopy and thermogravimetric analysis showed an effective interaction of starch with isoleucine. Isoleucine formulated films showed the highest tensile strength, whereas malic acid-rich films showed better strain values.

Original languageEnglish
Pages (from-to)17-27
Number of pages11
JournalPolymer - Plastics Technology and Engineering
Volume57
Issue number1
DOIs
StatePublished - 2 Jan 2018
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2018 Taylor & Francis.

Keywords

  • Amphiphilic
  • mechanical properties
  • plasticizer
  • retrogradation
  • thermoplastic starch

ASJC Scopus subject areas

  • Materials Science (miscellaneous)
  • General Chemical Engineering
  • Polymers and Plastics
  • Materials Chemistry

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