Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

Samir Barman; Hiroyasu Furukawa; Olivier Blacque; Koushik Venkatesan; Omar M. Yaghi; Guo Xin Jin; Heinz Berke

doi:10.1039/c1cc14387e

Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

Samir Barman
, Hiroyasu Furukawa^*
, Olivier Blacque
, Koushik Venkatesan
, Omar M. Yaghi
, Guo Xin Jin
, Heinz Berke

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.

Original language	English
Pages (from-to)	11882-11884
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	43
DOIs	https://doi.org/10.1039/c1cc14387e
State	Published - 21 Nov 2011
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c1cc14387e

Cite this

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abstract = "Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.",

author = "Samir Barman and Hiroyasu Furukawa and Olivier Blacque and Koushik Venkatesan and Yaghi, \{Omar M.\} and Jin, \{Guo Xin\} and Heinz Berke",

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AU - Barman, Samir

AU - Furukawa, Hiroyasu

AU - Blacque, Olivier

AU - Venkatesan, Koushik

AU - Yaghi, Omar M.

AU - Jin, Guo Xin

AU - Berke, Heinz

PY - 2011/11/21

Y1 - 2011/11/21

N2 - Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.

AB - Two novel 3D MOFs, namely MOF-647A and MOF-648 (previously unknown trinodal 4-connected net), comprised of Cu ions and pyrazole-3,5-dicarboxylate were synthesized and characterized. A strategy for incorporating open metal sites in MOFs was investigated by utilizing an in situ generated metal-linker complex as a precursor to construct MOF-648.

UR - https://www.scopus.com/pages/publications/80054907530

U2 - 10.1039/c1cc14387e

DO - 10.1039/c1cc14387e

M3 - Article

AN - SCOPUS:80054907530

SN - 1359-7345

VL - 47

SP - 11882

EP - 11884

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Incorporation of active metal sites in MOFs via in situ generated ligand deficient metal-linker complexes

Abstract

ASJC Scopus subject areas

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