Hydrothermally fabricated NdTe hollow shells thermally vaporized on Ni foam for water-splitting in alkaline media

Khadijah Mohammedsaleh Katubi, Mehar Un Nisa, Sumaira Manzoor, Zahoor Ahmad, Abdul Ghafoor Abid, Muhammad Abdullah, Mohammed Sultan Al-Buriahi, Muhammad Naeem Ashiq*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

Electrochemical water-splitting is not sparingly viable due to the slow anodic oxygen evolution reaction (OER). The need to engineer and fabricate electro-catalysts of low over-potential for water oxidation necessitates using readily available technologies and precursors. In the present study, OER electro-catalyst with composition neodymium telluride hollow shells vaporized on Ni Foam (NdTe-HS/NF) is fabricated at a substantially lower energy cost than other abundant metal-containing catalytic structures. The catalytic system functions properly, starting the oxygen evolution process at an over-potential of 301 mV vs. RHE, attaining a current density of 10 mA cm−2 and a modest Tafel slope of 91 mV dec−1 is also achieved. This tafel slope value suggests the presence of an electron/proton transfer channel. The catalyst sustains a constant current density over lengthy periods of up to 9 h of water electrolysis testing. Because of an easily accessible production technique, NdTe-HS/NF maintains its integrity, form, and chemical profile even after several hours of nonstop water electrolysis.

Original languageEnglish
Article number882
JournalApplied Physics A: Materials Science and Processing
Volume128
Issue number10
DOIs
StatePublished - Oct 2022
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.

Keywords

  • Alkaline media
  • Hollow shell
  • NdTe
  • OER

ASJC Scopus subject areas

  • General Chemistry
  • General Materials Science

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