Hydrothermal synthesis of ZnO-Ga2O3-Al 2O3 spinel for NO reduction by hydrocarbon under oxygen-rich conditions

Md Hasan Zahir; Shingo Katayama; Masanobu Awano

doi:10.1023/b:catl.0000017068.22414.4c

Hydrothermal synthesis of ZnO-Ga₂O₃-Al ₂O₃ spinel for NO reduction by hydrocarbon under oxygen-rich conditions

Md Hasan Zahir^*
, Shingo Katayama
, Masanobu Awano

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Spinel powders with addition of ZnO into Ga₂O ₃-Al₂O₃ were synthesized from a mixed solution of nitrate salts in the presence of aqueous ammonium carbonate under hydrothermal conditions at 150°C for 48 h. The crystallization of the spinel was promoted by an increase in reaction temperature and time. This powder was studied for the selective reduction of NO with hydrocarbons (CH₄, C₂H₄, and C₃H₅) in the presence of oxygen. High durability was observed for the reduction of NO by C ₂H₄ in the presence of water vapor and sulfur oxides, maintaining a high stability over 100 h.

Original language	English
Pages (from-to)	145-150
Number of pages	6
Journal	Catalysis Letters
Volume	93
Issue number	3-4
DOIs	https://doi.org/10.1023/b:catl.0000017068.22414.4c
State	Published - Mar 2004
Externally published	Yes

Keywords

Hydrocarbons
Hydrothermal
NO reduction
Spinel type structure

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1023/b:catl.0000017068.22414.4c

Cite this

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title = "Hydrothermal synthesis of ZnO-Ga2O3-Al 2O3 spinel for NO reduction by hydrocarbon under oxygen-rich conditions",

abstract = "Spinel powders with addition of ZnO into Ga2O 3-Al2O3 were synthesized from a mixed solution of nitrate salts in the presence of aqueous ammonium carbonate under hydrothermal conditions at 150°C for 48 h. The crystallization of the spinel was promoted by an increase in reaction temperature and time. This powder was studied for the selective reduction of NO with hydrocarbons (CH4, C2H4, and C3H5) in the presence of oxygen. High durability was observed for the reduction of NO by C 2H4 in the presence of water vapor and sulfur oxides, maintaining a high stability over 100 h.",

keywords = "Hydrocarbons, Hydrothermal, NO reduction, Spinel type structure",

author = "Zahir, \{Md Hasan\} and Shingo Katayama and Masanobu Awano",

year = "2004",

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doi = "10.1023/b:catl.0000017068.22414.4c",

language = "English",

volume = "93",

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journal = "Catalysis Letters",

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T1 - Hydrothermal synthesis of ZnO-Ga2O3-Al 2O3 spinel for NO reduction by hydrocarbon under oxygen-rich conditions

AU - Zahir, Md Hasan

AU - Katayama, Shingo

AU - Awano, Masanobu

PY - 2004/3

Y1 - 2004/3

N2 - Spinel powders with addition of ZnO into Ga2O 3-Al2O3 were synthesized from a mixed solution of nitrate salts in the presence of aqueous ammonium carbonate under hydrothermal conditions at 150°C for 48 h. The crystallization of the spinel was promoted by an increase in reaction temperature and time. This powder was studied for the selective reduction of NO with hydrocarbons (CH4, C2H4, and C3H5) in the presence of oxygen. High durability was observed for the reduction of NO by C 2H4 in the presence of water vapor and sulfur oxides, maintaining a high stability over 100 h.

AB - Spinel powders with addition of ZnO into Ga2O 3-Al2O3 were synthesized from a mixed solution of nitrate salts in the presence of aqueous ammonium carbonate under hydrothermal conditions at 150°C for 48 h. The crystallization of the spinel was promoted by an increase in reaction temperature and time. This powder was studied for the selective reduction of NO with hydrocarbons (CH4, C2H4, and C3H5) in the presence of oxygen. High durability was observed for the reduction of NO by C 2H4 in the presence of water vapor and sulfur oxides, maintaining a high stability over 100 h.

KW - Hydrocarbons

KW - Hydrothermal

KW - NO reduction

KW - Spinel type structure

UR - https://www.scopus.com/pages/publications/2142655048

U2 - 10.1023/b:catl.0000017068.22414.4c

DO - 10.1023/b:catl.0000017068.22414.4c

M3 - Article

AN - SCOPUS:2142655048

SN - 1011-372X

VL - 93

SP - 145

EP - 150

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -