Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor

Sultan Ahmed; M. Parvaz; Rahul Johari; M. Bilal; Sultan Ahmad; M. Zaid; S. Hussain; Islamuddin; Zishan H. Khan; M. Rafat

doi:10.1063/1.5032407

Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor

Sultan Ahmed^*
, M. Parvaz
, Rahul Johari
, M. Bilal
, Sultan Ahmad
, M. Zaid
, S. Hussain
, Islamuddin
, Zishan H. Khan
, M. Rafat

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

4 Scopus citations

Abstract

This work reports the successful preparation of Poly (3,4-ethylenedioxythiophene) (PEDOT) from monomer ethylenedioxythiophene (EDOT), employing hydrothermal method. The structure of the prepared sample was characterized by Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) and the results indicates the successful polymerization of EDOT to the formation of polymer PEDOT. The capacitive performance of the prepared sample were investigated in two-electrode assembly using aqueous solution of 6 M KOH. The assembled capacitor cell shows high rate capability which is evident from both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) studies. The observed CV patterns are almost rectangular even for high scan rates (∼30 V s^-1), confirming the high rate performance, while high knee frequency (∼1 kHz), and low response time (∼5.8 ms) observed by impedance analysis confirms the high rate capability of supercapacitor.

Original language	English
Title of host publication	2nd International Conference on Condensed Matter and Applied Physics, ICC 2017
Editors	Manoj Singh Shekhawat, Sudhir Bhardwaj, Bhuvneshwer Suthar
Publisher	American Institute of Physics Inc.
ISBN (Electronic)	9780735416482
DOIs	https://doi.org/10.1063/1.5032407
State	Published - 8 May 2018
Externally published	Yes
Event	2nd International Conference on Condensed Matter and Applied Physics, ICC 2017 - Bikaner, India Duration: 24 Nov 2017 → 25 Nov 2017

Publication series

Name	AIP Conference Proceedings
Volume	1953
ISSN (Print)	0094-243X
ISSN (Electronic)	1551-7616

Conference

Conference	2nd International Conference on Condensed Matter and Applied Physics, ICC 2017
Country/Territory	India
City	Bikaner
Period	24/11/17 → 25/11/17

Bibliographical note

Publisher Copyright:
© 2018 Author(s).

ASJC Scopus subject areas

General Physics and Astronomy

Access to Document

10.1063/1.5032407

Cite this

Ahmed, S., Parvaz, M., Johari, R., Bilal, M., Ahmad, S., Zaid, M., Hussain, S., Islamuddin, Khan, Z. H., & Rafat, M. (2018). Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor. In M. S. Shekhawat, S. Bhardwaj, & B. Suthar (Eds.), 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017 Article 030072 (AIP Conference Proceedings; Vol. 1953). American Institute of Physics Inc.. https://doi.org/10.1063/1.5032407

Ahmed, Sultan ; Parvaz, M. ; Johari, Rahul et al. / Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor. 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017. editor / Manoj Singh Shekhawat ; Sudhir Bhardwaj ; Bhuvneshwer Suthar. American Institute of Physics Inc., 2018. (AIP Conference Proceedings).

@inproceedings{ed055eb732b844f6ac3d4c8ad7f65b55,

title = "Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor",

abstract = "This work reports the successful preparation of Poly (3,4-ethylenedioxythiophene) (PEDOT) from monomer ethylenedioxythiophene (EDOT), employing hydrothermal method. The structure of the prepared sample was characterized by Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) and the results indicates the successful polymerization of EDOT to the formation of polymer PEDOT. The capacitive performance of the prepared sample were investigated in two-electrode assembly using aqueous solution of 6 M KOH. The assembled capacitor cell shows high rate capability which is evident from both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) studies. The observed CV patterns are almost rectangular even for high scan rates (∼30 V s-1), confirming the high rate performance, while high knee frequency (∼1 kHz), and low response time (∼5.8 ms) observed by impedance analysis confirms the high rate capability of supercapacitor.",

author = "Sultan Ahmed and M. Parvaz and Rahul Johari and M. Bilal and Sultan Ahmad and M. Zaid and S. Hussain and Islamuddin and Khan, \{Zishan H.\} and M. Rafat",

note = "Publisher Copyright: {\textcopyright} 2018 Author(s).; 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017 ; Conference date: 24-11-2017 Through 25-11-2017",

year = "2018",

month = may,

day = "8",

doi = "10.1063/1.5032407",

language = "English",

series = "AIP Conference Proceedings",

publisher = "American Institute of Physics Inc.",

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Ahmed, S, Parvaz, M, Johari, R, Bilal, M, Ahmad, S, Zaid, M, Hussain, S, Islamuddin, Khan, ZH & Rafat, M 2018, Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor. in MS Shekhawat, S Bhardwaj & B Suthar (eds), 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017., 030072, AIP Conference Proceedings, vol. 1953, American Institute of Physics Inc., 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017, Bikaner, India, 24/11/17. https://doi.org/10.1063/1.5032407

Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor. / Ahmed, Sultan; Parvaz, M.; Johari, Rahul et al.
2nd International Conference on Condensed Matter and Applied Physics, ICC 2017. ed. / Manoj Singh Shekhawat; Sudhir Bhardwaj; Bhuvneshwer Suthar. American Institute of Physics Inc., 2018. 030072 (AIP Conference Proceedings; Vol. 1953).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor

AU - Ahmed, Sultan

AU - Parvaz, M.

AU - Johari, Rahul

AU - Bilal, M.

AU - Ahmad, Sultan

AU - Zaid, M.

AU - Hussain, S.

AU - Islamuddin,

AU - Khan, Zishan H.

AU - Rafat, M.

PY - 2018/5/8

Y1 - 2018/5/8

N2 - This work reports the successful preparation of Poly (3,4-ethylenedioxythiophene) (PEDOT) from monomer ethylenedioxythiophene (EDOT), employing hydrothermal method. The structure of the prepared sample was characterized by Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) and the results indicates the successful polymerization of EDOT to the formation of polymer PEDOT. The capacitive performance of the prepared sample were investigated in two-electrode assembly using aqueous solution of 6 M KOH. The assembled capacitor cell shows high rate capability which is evident from both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) studies. The observed CV patterns are almost rectangular even for high scan rates (∼30 V s-1), confirming the high rate performance, while high knee frequency (∼1 kHz), and low response time (∼5.8 ms) observed by impedance analysis confirms the high rate capability of supercapacitor.

AB - This work reports the successful preparation of Poly (3,4-ethylenedioxythiophene) (PEDOT) from monomer ethylenedioxythiophene (EDOT), employing hydrothermal method. The structure of the prepared sample was characterized by Fourier transform infrared (FTIR) spectroscopy, and X-ray diffraction (XRD) and the results indicates the successful polymerization of EDOT to the formation of polymer PEDOT. The capacitive performance of the prepared sample were investigated in two-electrode assembly using aqueous solution of 6 M KOH. The assembled capacitor cell shows high rate capability which is evident from both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) studies. The observed CV patterns are almost rectangular even for high scan rates (∼30 V s-1), confirming the high rate performance, while high knee frequency (∼1 kHz), and low response time (∼5.8 ms) observed by impedance analysis confirms the high rate capability of supercapacitor.

UR - https://www.scopus.com/pages/publications/85047328936

U2 - 10.1063/1.5032407

DO - 10.1063/1.5032407

M3 - Conference contribution

AN - SCOPUS:85047328936

T3 - AIP Conference Proceedings

BT - 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017

A2 - Shekhawat, Manoj Singh

A2 - Bhardwaj, Sudhir

A2 - Suthar, Bhuvneshwer

PB - American Institute of Physics Inc.

T2 - 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017

Y2 - 24 November 2017 through 25 November 2017

ER -

Ahmed S, Parvaz M, Johari R, Bilal M, Ahmad S, Zaid M et al. Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor. In Shekhawat MS, Bhardwaj S, Suthar B, editors, 2nd International Conference on Condensed Matter and Applied Physics, ICC 2017. American Institute of Physics Inc. 2018. 030072. (AIP Conference Proceedings). doi: 10.1063/1.5032407

Hydrothermal synthesis of poly(3,4-ethylenedioxythiophene) for high-rate performance supercapacitor

Abstract

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Bibliographical note

ASJC Scopus subject areas

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