Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles

Meixuan Tan; Yugen Zhang; Jackie Y. Ying

doi:10.1002/adsc.200800815

Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles

Meixuan Tan, Yugen Zhang^*, Jackie Y. Ying

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

78 Scopus citations

Abstract

N-Heterocyclic carbene (NHC)-catalyzed ketone/imine hydrosilylation, silane alcohol condensation and asymmetric ketone hydrosilylation reactions were demonstrated for the first time over solid, main-chain poly-NHC particles. The stable and robust poly-NHC particles were easily recovered, and exhibited good catalytic recyclability. A novel chiral induction protocol with a cheap and easily accessible secondary alcohol as the chiral source was also developed in this catalytic system.

Original language	English
Pages (from-to)	1390-1394
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	351
Issue number	9
DOIs	https://doi.org/10.1002/adsc.200800815
State	Published - Jun 2009
Externally published	Yes

Keywords

Heterogeneous catalysis
Hydrosilylation
N-heterocyclic carbenes
Organocatalysis

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/adsc.200800815

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title = "Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles",

abstract = "N-Heterocyclic carbene (NHC)-catalyzed ketone/imine hydrosilylation, silane alcohol condensation and asymmetric ketone hydrosilylation reactions were demonstrated for the first time over solid, main-chain poly-NHC particles. The stable and robust poly-NHC particles were easily recovered, and exhibited good catalytic recyclability. A novel chiral induction protocol with a cheap and easily accessible secondary alcohol as the chiral source was also developed in this catalytic system.",

keywords = "Heterogeneous catalysis, Hydrosilylation, N-heterocyclic carbenes, Organocatalysis",

author = "Meixuan Tan and Yugen Zhang and Ying, \{Jackie Y.\}",

year = "2009",

month = jun,

doi = "10.1002/adsc.200800815",

language = "English",

volume = "351",

pages = "1390--1394",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

publisher = "Wiley-VCH Verlag",

number = "9",

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TY - JOUR

T1 - Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles

AU - Tan, Meixuan

AU - Zhang, Yugen

AU - Ying, Jackie Y.

PY - 2009/6

Y1 - 2009/6

N2 - N-Heterocyclic carbene (NHC)-catalyzed ketone/imine hydrosilylation, silane alcohol condensation and asymmetric ketone hydrosilylation reactions were demonstrated for the first time over solid, main-chain poly-NHC particles. The stable and robust poly-NHC particles were easily recovered, and exhibited good catalytic recyclability. A novel chiral induction protocol with a cheap and easily accessible secondary alcohol as the chiral source was also developed in this catalytic system.

AB - N-Heterocyclic carbene (NHC)-catalyzed ketone/imine hydrosilylation, silane alcohol condensation and asymmetric ketone hydrosilylation reactions were demonstrated for the first time over solid, main-chain poly-NHC particles. The stable and robust poly-NHC particles were easily recovered, and exhibited good catalytic recyclability. A novel chiral induction protocol with a cheap and easily accessible secondary alcohol as the chiral source was also developed in this catalytic system.

KW - Heterogeneous catalysis

KW - Hydrosilylation

KW - N-heterocyclic carbenes

KW - Organocatalysis

UR - https://www.scopus.com/pages/publications/67549109260

U2 - 10.1002/adsc.200800815

DO - 10.1002/adsc.200800815

M3 - Article

AN - SCOPUS:67549109260

SN - 1615-4150

VL - 351

SP - 1390

EP - 1394

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 9

ER -

Hydrosilylation of ketone and imine over poly-N-heterocyclic carbene particles

Abstract

Keywords

ASJC Scopus subject areas

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