Highly efficient solar light-driven photocatalytic hydrogen production over Cu/FCNTs-titania quantum dots-based heterostructures

The need for clean and eco-friendly energy sources has increased enormously over the years due to adverse impacts caused by the detrimental fossil fuel energy sources on the environment. This work reports the safest and most efficient route for hydrogen generation using solar light receptive functionalized carbon nanotubes-titania quantum dots (FCNT-TQDs) as photocatalysts under the influence of solar light irradiation. Predominantly, dual capability of CNT as co-catalyst and photo-sensitizer reduced the recombination rate of charge carriers, and facilitated the efficient light harvesting. The bulk production of hydrogen via water harvesting is considered, wherein photocatalyst synthesized was tuned by the optimum addition of copper to achieve higher production rate of hydrogen up to 54.4 mmol h⁻¹g⁻¹, nearly 25-folds higher than that of pristine TiO₂ quantum dots. Addition of copper has a crucial role in improving the rate of hydrogen generation. The ternary composite exhibited 5.4-times higher hydrogen production compared to FCNT-TQDs composite.