High resolution XPS study of oxide layers grown on Ge substrates

N. Tabet*, M. Faiz, N. M. Hamdan, Z. Hussain

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

80 Scopus citations

Abstract

High resolution X-ray photoelectron spectroscopy (XPS) was used to analyze thin layers of germanium oxide grown on germanium substrates under various conditions. The results reveal the presence of high density of electron states located at the oxide/germanium interface that lead to the energy band bending. The surface of native oxide layers and that of thin oxide layer grown under dry oxygen correspond to GeO2 composition. Under Ar etching, lower oxidation states were revealed. Short in situ heat treatment at T = 673 K under ultrahigh vacuum leads to the removal of the oxide layer. In addition, the analysis of the layer grown at T = 653 K under dry oxygen suggests that carbides form at the oxide/substrate interface.

Original languageEnglish
Pages (from-to)68-72
Number of pages5
JournalSurface Science
Volume523
Issue number1-2
DOIs
StatePublished - 10 Jan 2003

Bibliographical note

Funding Information:
This work was partially supported by the U.S. Department of Energy under contract no. DE-AC03-76SF00098. Faiz and Tabet would like to thank King Fahd University of Petroleum and Minerals for its support.

Keywords

  • Germanium
  • Oxidation
  • Surface electronic phenomena (work function, surface potential, surface states, etc.)
  • X-ray photoelectron spectroscopy

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films
  • Materials Chemistry

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