Abstract
High resolution X-ray photoelectron spectroscopy (XPS) was used to analyze thin layers of germanium oxide grown on germanium substrates under various conditions. The results reveal the presence of high density of electron states located at the oxide/germanium interface that lead to the energy band bending. The surface of native oxide layers and that of thin oxide layer grown under dry oxygen correspond to GeO2 composition. Under Ar etching, lower oxidation states were revealed. Short in situ heat treatment at T = 673 K under ultrahigh vacuum leads to the removal of the oxide layer. In addition, the analysis of the layer grown at T = 653 K under dry oxygen suggests that carbides form at the oxide/substrate interface.
| Original language | English |
|---|---|
| Pages (from-to) | 68-72 |
| Number of pages | 5 |
| Journal | Surface Science |
| Volume | 523 |
| Issue number | 1-2 |
| DOIs | |
| State | Published - 10 Jan 2003 |
Bibliographical note
Funding Information:This work was partially supported by the U.S. Department of Energy under contract no. DE-AC03-76SF00098. Faiz and Tabet would like to thank King Fahd University of Petroleum and Minerals for its support.
Keywords
- Germanium
- Oxidation
- Surface electronic phenomena (work function, surface potential, surface states, etc.)
- X-ray photoelectron spectroscopy
ASJC Scopus subject areas
- Condensed Matter Physics
- Surfaces and Interfaces
- Surfaces, Coatings and Films
- Materials Chemistry