High-efficient photocatalytic degradation of commercial drugs for pharmaceutical wastewater treatment prospects: A case study of Ag/g-C₃N₄/ZnO nanocomposite materials

Pharmaceutical drugs' removal from wastewater by photocatalytic oxidation process is considered as an attractive approach and environmentally friendly solution. This report aims to appraise the practical application potential of Ag/g-C₃N₄/ZnO nanorods toward the wastewater treatment of the pharmaceutical industry. The catalysts are synthesized by straightforward and environmentally-friendly strategies. Specifically, g-C₃N₄/ZnO nanorods heterostructure is constructed by a simple self-assembly method, and then Ag nanoparticles are decorated on g-C₃N₄/ZnO nanorods by a photoreduction route. The results show that three commercial drugs (paracetamol, amoxicillin, and cefalexin) with high concentration (40 mg L⁻¹) are significantly degraded in the existence of a small dosage of Ag/g-C₃N₄/ZnO nanorods (0.08 g L⁻¹). The Ag/g-C₃N₄/ZnO nanorods photocatalyst exhibits degradation performance of paracetamol higher 3.8, 1.8, 1.3 times than pristine g-C₃N₄, ZnO nanorods, and g-C₃N₄/ZnO nanorods. Furthermore, Ag/g-C₃N₄/ZnO nanorods have an excellent reusability and a chemical stability that achieved paracetamol degradation efficiency of 78% and remained chemical structure of the photocatalyst after five cycles. In addition, the photocatalytic mechanism explanation and comparison of photocatalytic drugs’ degradation ability have also been discussed in this study.