Heteropolyacid-catalyzed chemoselective oxidation of benzil derivatives to carboxylic esters by dioxygen

Bassam El Ali; Abdel Moneim El-Ghanam; Mohammed Fettouhi

Heteropolyacid-catalyzed chemoselective oxidation of benzil derivatives to carboxylic esters by dioxygen

Bassam El Ali^*
, Abdel Moneim El-Ghanam
, Mohammed Fettouhi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Benzil derivatives are catalytically oxidized by the heteropolyacids of general formula H_3+nPMo_12-nV_nO₄₀, xH₂O (HPA-n, n = 1-4, x = 30-36) with dioxygen under mild conditions. High yields and excellent selectivity of mono- and dicarboxylic esters were obtained in the presence of primary alcohols or diols.

Original language	English
Pages (from-to)	3-10
Number of pages	8
Journal	Arabian Journal for Science and Engineering
Volume	26
Issue number	1 A
State	Published - Jan 2001

Keywords

Benzil
Carboxylic esters
Cleavage
Heteropolyacids
Oxidation
Vanadium

ASJC Scopus subject areas

General

Cite this

@article{bad09e76821443ef98255a205ad5643a,

title = "Heteropolyacid-catalyzed chemoselective oxidation of benzil derivatives to carboxylic esters by dioxygen",

abstract = "Benzil derivatives are catalytically oxidized by the heteropolyacids of general formula H3+nPMo12-nVnO40, xH2O (HPA-n, n = 1-4, x = 30-36) with dioxygen under mild conditions. High yields and excellent selectivity of mono- and dicarboxylic esters were obtained in the presence of primary alcohols or diols.",

keywords = "Benzil, Carboxylic esters, Cleavage, Heteropolyacids, Oxidation, Vanadium",

author = "\{El Ali\}, Bassam and El-Ghanam, \{Abdel Moneim\} and Mohammed Fettouhi",

year = "2001",

month = jan,

language = "English",

volume = "26",

pages = "3--10",

journal = "Arabian Journal for Science and Engineering",

issn = "2193-567X",

publisher = "Springer Nature",

number = "1 A",

}

TY - JOUR

T1 - Heteropolyacid-catalyzed chemoselective oxidation of benzil derivatives to carboxylic esters by dioxygen

AU - El Ali, Bassam

AU - El-Ghanam, Abdel Moneim

AU - Fettouhi, Mohammed

PY - 2001/1

Y1 - 2001/1

N2 - Benzil derivatives are catalytically oxidized by the heteropolyacids of general formula H3+nPMo12-nVnO40, xH2O (HPA-n, n = 1-4, x = 30-36) with dioxygen under mild conditions. High yields and excellent selectivity of mono- and dicarboxylic esters were obtained in the presence of primary alcohols or diols.

AB - Benzil derivatives are catalytically oxidized by the heteropolyacids of general formula H3+nPMo12-nVnO40, xH2O (HPA-n, n = 1-4, x = 30-36) with dioxygen under mild conditions. High yields and excellent selectivity of mono- and dicarboxylic esters were obtained in the presence of primary alcohols or diols.

KW - Benzil

KW - Carboxylic esters

KW - Cleavage

KW - Heteropolyacids

KW - Oxidation

KW - Vanadium

UR - https://www.scopus.com/pages/publications/0035613757

M3 - Article

AN - SCOPUS:0035613757

SN - 2193-567X

VL - 26

SP - 3

EP - 10

JO - Arabian Journal for Science and Engineering

JF - Arabian Journal for Science and Engineering

IS - 1 A

ER -

Heteropolyacid-catalyzed chemoselective oxidation of benzil derivatives to carboxylic esters by dioxygen

Abstract

Keywords

ASJC Scopus subject areas

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