Heterogeneous heck catalysis with palladium-grafted molecular sieves

Christian P. Mehnert; David W. Weaver; Jackie Y. Ying

doi:10.1021/ja971637u

Heterogeneous heck catalysis with palladium-grafted molecular sieves

Christian P. Mehnert
, David W. Weaver
, Jackie Y. Ying^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

444 Scopus citations

Abstract

The synthesis and characterization of palladium-grafted mesoporous MCM- 41 material, designated Pd-TMS11, are described. The material is investigated for carbon-carbon coupling reactions (Heck catalysis) with activated and nonactivated aryl substrates. For the preparation of the new catalyst, a volatile organometallic precursor is reacted in the gas phase with the surface of the porous framework, generating a highly dispersed metal deposition. The ultrahigh surface area, the large pore opening, and the highly dispersed catalyst species in Pd-TMS11 material create one of the most active heterogeneous catalysts for Heck reactions.

Original language	English
Pages (from-to)	12289-12296
Number of pages	8
Journal	Journal of the American Chemical Society
Volume	120
Issue number	47
DOIs	https://doi.org/10.1021/ja971637u
State	Published - 2 Dec 1998
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja971637u

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title = "Heterogeneous heck catalysis with palladium-grafted molecular sieves",

abstract = "The synthesis and characterization of palladium-grafted mesoporous MCM- 41 material, designated Pd-TMS11, are described. The material is investigated for carbon-carbon coupling reactions (Heck catalysis) with activated and nonactivated aryl substrates. For the preparation of the new catalyst, a volatile organometallic precursor is reacted in the gas phase with the surface of the porous framework, generating a highly dispersed metal deposition. The ultrahigh surface area, the large pore opening, and the highly dispersed catalyst species in Pd-TMS11 material create one of the most active heterogeneous catalysts for Heck reactions.",

author = "Mehnert, \{Christian P.\} and Weaver, \{David W.\} and Ying, \{Jackie Y.\}",

year = "1998",

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AU - Mehnert, Christian P.

AU - Weaver, David W.

AU - Ying, Jackie Y.

PY - 1998/12/2

Y1 - 1998/12/2

N2 - The synthesis and characterization of palladium-grafted mesoporous MCM- 41 material, designated Pd-TMS11, are described. The material is investigated for carbon-carbon coupling reactions (Heck catalysis) with activated and nonactivated aryl substrates. For the preparation of the new catalyst, a volatile organometallic precursor is reacted in the gas phase with the surface of the porous framework, generating a highly dispersed metal deposition. The ultrahigh surface area, the large pore opening, and the highly dispersed catalyst species in Pd-TMS11 material create one of the most active heterogeneous catalysts for Heck reactions.

AB - The synthesis and characterization of palladium-grafted mesoporous MCM- 41 material, designated Pd-TMS11, are described. The material is investigated for carbon-carbon coupling reactions (Heck catalysis) with activated and nonactivated aryl substrates. For the preparation of the new catalyst, a volatile organometallic precursor is reacted in the gas phase with the surface of the porous framework, generating a highly dispersed metal deposition. The ultrahigh surface area, the large pore opening, and the highly dispersed catalyst species in Pd-TMS11 material create one of the most active heterogeneous catalysts for Heck reactions.

UR - https://www.scopus.com/pages/publications/0032477347

U2 - 10.1021/ja971637u

DO - 10.1021/ja971637u

M3 - Article

AN - SCOPUS:0032477347

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SP - 12289

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 47

ER -

Heterogeneous heck catalysis with palladium-grafted molecular sieves

Abstract

ASJC Scopus subject areas

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