Heterogeneous Chemiluminescence from Gas-Solid Phase Interactions of Ozone with Alcohols, Phenols, and Saccharides

Dingkun Zhang; Yongzan Zheng; Xiangnan Dou; Haifeng Lin; Syed Niaz Ali Shah; Jin Ming Lin

doi:10.1021/acs.langmuir.7b00481

Heterogeneous Chemiluminescence from Gas-Solid Phase Interactions of Ozone with Alcohols, Phenols, and Saccharides

Dingkun Zhang
, Yongzan Zheng
, Xiangnan Dou
, Haifeng Lin
, Syed Niaz Ali Shah
, Jin Ming Lin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Gas-solid phase reactions between ozone (O₃) and three representative solids (alcohols, phenols, and saccharides) were investigated through a heterogeneous chemiluminescence (CL) strategy. When interactions between these two species occurred at the surface of the solid powder, an obvious CL effect was obtained. This performance could be attributed to the evolution of a ROOOH intermediate, which subsequently released emissive¹O₂ species. This is the first report analyzing the gas-solid phase CL performance of O₃ with alcohols, phenols, and saccharides. It is believed that this strategy can be extended to applications in other gas-solid phase CL analyses utilizing the O₃ system. This has also created a novel area of gas-solid CL performance; thus, relevant processes and mechanisms can be deduced and identified.

Original language	English
Pages (from-to)	3666-3671
Number of pages	6
Journal	Langmuir
Volume	33
Issue number	15
DOIs	https://doi.org/10.1021/acs.langmuir.7b00481
State	Published - 18 Apr 2017
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2017 American Chemical Society.

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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Cite this

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title = "Heterogeneous Chemiluminescence from Gas-Solid Phase Interactions of Ozone with Alcohols, Phenols, and Saccharides",

abstract = "Gas-solid phase reactions between ozone (O3) and three representative solids (alcohols, phenols, and saccharides) were investigated through a heterogeneous chemiluminescence (CL) strategy. When interactions between these two species occurred at the surface of the solid powder, an obvious CL effect was obtained. This performance could be attributed to the evolution of a ROOOH intermediate, which subsequently released emissive1O2 species. This is the first report analyzing the gas-solid phase CL performance of O3 with alcohols, phenols, and saccharides. It is believed that this strategy can be extended to applications in other gas-solid phase CL analyses utilizing the O3 system. This has also created a novel area of gas-solid CL performance; thus, relevant processes and mechanisms can be deduced and identified.",

author = "Dingkun Zhang and Yongzan Zheng and Xiangnan Dou and Haifeng Lin and Shah, \{Syed Niaz Ali\} and Lin, \{Jin Ming\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = apr,

day = "18",

doi = "10.1021/acs.langmuir.7b00481",

language = "English",

volume = "33",

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TY - JOUR

T1 - Heterogeneous Chemiluminescence from Gas-Solid Phase Interactions of Ozone with Alcohols, Phenols, and Saccharides

AU - Zhang, Dingkun

AU - Zheng, Yongzan

AU - Dou, Xiangnan

AU - Lin, Haifeng

AU - Shah, Syed Niaz Ali

AU - Lin, Jin Ming

PY - 2017/4/18

Y1 - 2017/4/18

N2 - Gas-solid phase reactions between ozone (O3) and three representative solids (alcohols, phenols, and saccharides) were investigated through a heterogeneous chemiluminescence (CL) strategy. When interactions between these two species occurred at the surface of the solid powder, an obvious CL effect was obtained. This performance could be attributed to the evolution of a ROOOH intermediate, which subsequently released emissive1O2 species. This is the first report analyzing the gas-solid phase CL performance of O3 with alcohols, phenols, and saccharides. It is believed that this strategy can be extended to applications in other gas-solid phase CL analyses utilizing the O3 system. This has also created a novel area of gas-solid CL performance; thus, relevant processes and mechanisms can be deduced and identified.

AB - Gas-solid phase reactions between ozone (O3) and three representative solids (alcohols, phenols, and saccharides) were investigated through a heterogeneous chemiluminescence (CL) strategy. When interactions between these two species occurred at the surface of the solid powder, an obvious CL effect was obtained. This performance could be attributed to the evolution of a ROOOH intermediate, which subsequently released emissive1O2 species. This is the first report analyzing the gas-solid phase CL performance of O3 with alcohols, phenols, and saccharides. It is believed that this strategy can be extended to applications in other gas-solid phase CL analyses utilizing the O3 system. This has also created a novel area of gas-solid CL performance; thus, relevant processes and mechanisms can be deduced and identified.

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DO - 10.1021/acs.langmuir.7b00481

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SN - 0743-7463

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JO - Langmuir

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IS - 15

ER -

Heterogeneous Chemiluminescence from Gas-Solid Phase Interactions of Ozone with Alcohols, Phenols, and Saccharides

Abstract

Bibliographical note

ASJC Scopus subject areas

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