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Graphene oxide supported La/Co/Ni trimetallic nano-scale systems for photocatalytic remediation of 2-chlorophenol

  • Gaurav Sharma*
  • , Amit Kumar
  • , Mu Naushad
  • , Shweta Sharma
  • , Ayman A. Ghfar
  • , Tansir Ahamad
  • , Chuanling Si
  • , Florian J. Stadler
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Fabrication of highly active photocatalysts that can be utilized for water detoxification is the need of time. In present work, we have synthesized La/Co/Ni TNPs and graphene oxide (GO) supported La/Co/Ni trimetallic nanocomposite (La/Co/Ni@GO TNC) using simple microwave method. The potential application of TNPs and TNC has been explored for photodegradation of 2-chlorophenol (2-CP) under natural sunlight irradiations. Among the two, La/Co/Ni@GO TNC (71% in 300 min) exhibited better photocatalytic ability as compared to La/Co/Ni TNPs (57% in 300 min). The superior performance of La/Co/Ni@GO TNC is credited to the efficient charge transfer and reduced electron-hole recombination ability. The band structure analysis, scavenging experiments and terephthalic acid studies have made it possible to finalise a probable degradation mechanism for 2-CP.

Original languageEnglish
Article number111605
JournalJournal of Molecular Liquids
Volume294
DOIs
StatePublished - 15 Nov 2019
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2019 Elsevier B.V.

Keywords

  • 2-Chlorophenol
  • Graphene oxide
  • Photocatalytic degradation
  • Trimetallic nanocomposite
  • Trimetallic nanoparticles

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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