Gold-surface binding of molecular switches studied by Mössbauer spectroscopy

Patrick Homenya; Markus Messerschmidt; Muhammad Nawaz Tahir; Victor Martinez; Yajun Cheng; Jochen S. Gutmann; Michael Klein; Stefan Jung; Morris Wolff; Reza Saadat; Driss Nariaki; Roman Boča; Göstar Klingelhöfer; Wolfgang Tremel; Franz Renz

doi:10.1007/s10751-011-0426-1

Gold-surface binding of molecular switches studied by Mössbauer spectroscopy

Patrick Homenya^*, Markus Messerschmidt, Muhammad Nawaz Tahir, Victor Martinez, Yajun Cheng, Jochen S. Gutmann, Michael Klein, Stefan Jung, Morris Wolff, Reza Saadat, Driss Nariaki, Roman Boča, Göstar Klingelhöfer, Wolfgang Tremel, Franz Renz

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The nonanuclear coordination compound [Mo ^IV{(CN)Fe ^III(3-methyl-saldptn)} ₈]Cl ₄ exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. Mössbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.

Original language	English
Pages (from-to)	63-67
Number of pages	5
Journal	Hyperfine Interactions
Volume	205
Issue number	1-3
DOIs	https://doi.org/10.1007/s10751-011-0426-1
State	Published - Mar 2012
Externally published	Yes

Bibliographical note

Funding Information:
Acknowledgements Grant Agencies (Slovakia: VEGA 1/0052/11, VVCE 0004-07; Germany: Leibniz University, LNQE, ZFM; Uni Mainz, MWFZ; DAAD; DFG Re-1627; EU: Structural Funds, Interreg IIIA) are acknowledged for the financial support.

Keywords

Au surface
Mössbauer spectroscopy
Nonanuclear
Self-assembled monolayer
Spin crossover

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Nuclear and High Energy Physics
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1007/s10751-011-0426-1

Cite this

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title = "Gold-surface binding of molecular switches studied by M{\"o}ssbauer spectroscopy",

abstract = "The nonanuclear coordination compound [Mo IV\{(CN)Fe III(3-methyl-saldptn)\} 8]Cl 4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. M{\"o}ssbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.",

keywords = "Au surface, M{\"o}ssbauer spectroscopy, Nonanuclear, Self-assembled monolayer, Spin crossover",

author = "Patrick Homenya and Markus Messerschmidt and Tahir, \{Muhammad Nawaz\} and Victor Martinez and Yajun Cheng and Gutmann, \{Jochen S.\} and Michael Klein and Stefan Jung and Morris Wolff and Reza Saadat and Driss Nariaki and Roman Bo{\v c}a and G{\"o}star Klingelh{\"o}fer and Wolfgang Tremel and Franz Renz",

note = "Funding Information: Acknowledgements Grant Agencies (Slovakia: VEGA 1/0052/11, VVCE 0004-07; Germany: Leibniz University, LNQE, ZFM; Uni Mainz, MWFZ; DAAD; DFG Re-1627; EU: Structural Funds, Interreg IIIA) are acknowledged for the financial support.",

year = "2012",

month = mar,

doi = "10.1007/s10751-011-0426-1",

language = "English",

volume = "205",

pages = "63--67",

journal = "Hyperfine Interactions",

issn = "0304-3843",

publisher = "Springer Nature",

number = "1-3",

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T1 - Gold-surface binding of molecular switches studied by Mössbauer spectroscopy

AU - Homenya, Patrick

AU - Messerschmidt, Markus

AU - Tahir, Muhammad Nawaz

AU - Martinez, Victor

AU - Cheng, Yajun

AU - Gutmann, Jochen S.

AU - Klein, Michael

AU - Jung, Stefan

AU - Wolff, Morris

AU - Saadat, Reza

AU - Nariaki, Driss

AU - Boča, Roman

AU - Klingelhöfer, Göstar

AU - Tremel, Wolfgang

AU - Renz, Franz

N1 - Funding Information: Acknowledgements Grant Agencies (Slovakia: VEGA 1/0052/11, VVCE 0004-07; Germany: Leibniz University, LNQE, ZFM; Uni Mainz, MWFZ; DAAD; DFG Re-1627; EU: Structural Funds, Interreg IIIA) are acknowledged for the financial support.

PY - 2012/3

Y1 - 2012/3

N2 - The nonanuclear coordination compound [Mo IV{(CN)Fe III(3-methyl-saldptn)} 8]Cl 4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. Mössbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.

AB - The nonanuclear coordination compound [Mo IV{(CN)Fe III(3-methyl-saldptn)} 8]Cl 4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. Mössbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.

KW - Au surface

KW - Mössbauer spectroscopy

KW - Nonanuclear

KW - Self-assembled monolayer

KW - Spin crossover

UR - https://www.scopus.com/pages/publications/84859584744

U2 - 10.1007/s10751-011-0426-1

DO - 10.1007/s10751-011-0426-1

M3 - Article

AN - SCOPUS:84859584744

SN - 0304-3843

VL - 205

SP - 63

EP - 67

JO - Hyperfine Interactions

JF - Hyperfine Interactions

IS - 1-3

ER -

Gold-surface binding of molecular switches studied by Mössbauer spectroscopy

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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