Gelatin: A green corrosion inhibitor for carbon steel in oil well acidizing environment

K. Haruna, I. B. Obot*, N. K. Ankah, A. A. Sorour, T. A. Saleh

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

126 Scopus citations

Abstract

Corrosion inhibition performance of an environmentally benign compound, gelatin on X60 steel in 15% hydrochloric acid (HCl) at 25 °C, which simulate oil well acidizing environment was investigated in this study. The inhibition efficiency of the gelatin was examined using weight loss, potentiodynamic polarization (PDP), linear polarization (LPR), and electrochemical impedance spectroscopy (EIS) measurements techniques. Both the weight loss and the electrochemical results showed that the gelatin exhibits high inhibition efficiency and the inhibition efficiency increases with increasing gelatin concentration. The addition of low concentration of potassium iodide improves the inhibition efficiency of gelatin considerably. The ATR-FTIR and SEM/EDX surface morphology analyses provide evidence of formation of protective gelatin film on the metal surface. The gelatin molecules are predicted to adsorb on the metal surface through an interaction between the nitrogen and oxygen atoms of gelatin and the metal surface to form a metal/gelatin complex on the metal surface.

Original languageEnglish
Pages (from-to)515-525
Number of pages11
JournalJournal of Molecular Liquids
Volume264
DOIs
StatePublished - 15 Aug 2018

Bibliographical note

Publisher Copyright:
© 2018 Elsevier B.V.

Keywords

  • Acidizing
  • Carbon steel
  • Corrosion inhibitors
  • Electrochemical techniques
  • Gelatin

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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