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First-Principle Study on the Effect of Pi-Spacers on Small Molecule Acceptors: Quantum Design of Organic Solar Cells and NLO Compounds

  • Muhammad Ramzan Saeed Ashraf Janjua*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Abstract: In this study, we have designed small molecule acceptors for organic solar cells by the modification of pi-spacers. Different thiophene derivatives and furan were used as pi-spacers. Theoretical calculations were performed to understand the effect on energy level and spectral profile. We have also predicted some performance parameters for solar cells. The results indicate that pi-spacers have minor effect on LUMO energy levels, while have notice able effect on HOMO. P2 (dithiophene) have shown highest performance among all the studied pi-spacers (P0–P4). These results specify that the quantum designing of acceptors with slight change in energy level is an effective way to get high efficiency with same donor. Graphical Abstract: Molecular framework for designing of small-molecule acceptors towards quantum design of organic solar cells and NLO compounds.

Original languageEnglish
Pages (from-to)2419-2431
Number of pages13
JournalJournal of Cluster Science
Volume28
Issue number5
DOIs
StatePublished - 1 Sep 2017

Bibliographical note

Publisher Copyright:
© 2017, Springer Science+Business Media New York.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • DFT
  • NLO
  • Pi-spacers
  • Solar cell
  • Thiophene

ASJC Scopus subject areas

  • Biochemistry
  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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