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Facile synthesis of strontium selenide supported copper sulfide hybrid nanosheets as an efficient electrode for high-performance OER

  • Ali Junaid
  • , Muhammad Abdullah
  • , Nigarish Bano
  • , Faiqa Noreen
  • , Syed Imran Abbas Shah
  • , Razan A. Alshgari
  • , Saikh Mohammad
  • , Sumaira Manzoor
  • , Muhammad Fahad Ehsan
  • , Muhammad Naeem Ashiq*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

61 Scopus citations

Abstract

To drive clean and sustainable fuel production via water electrolysis, development of high-performing, cost-effective electrocatalysts rich in earth elements without relying on precious metals or costly materials is crucial. In this study, strontium selenide (SrSe), copper sulfide (CuS), and composite SrSe@CuS via a traditional coprecipitate method under alkaline conditions are synthesized. Characterization techniques including X-ray diffraction, Transmission electron microscopy, Field emission scanning electron microscopy, and Brunauer–Emmett–Teller surface area analysis are employed to analyze the structure, morphology, and surface characteristics. The larger surface area of 123 m2 g−1 and lower crystalline size (46.43 nm) of SrSe@CuS nanosheets show more active sites for oxygen evolution reaction. The oxygen evolution activity displayed overpotentials of 290 mV, a lower tafel slope of 67 mV dec−1, and Lower charge transfer resistance (RCT) values of SrSe@CuS nanosheets (1.82 Ω) surpassing the individual SrSe and CuS nanosheets. Notably, the SrSe@CuS nanosheets exhibited remarkable stability, maintaining an oxygen evolution reaction (OER) activity of 10 mA cm−2 for over 50 h and sustaining a negligible loss in performance even after 50,000 cycles of repetitive cyclivoltammetry scans. These findings highlight their potential applicability in energy conversion and storage systems. Graphical abstract: (Figure presented.)

Original languageEnglish
Pages (from-to)469-481
Number of pages13
JournalJournal of the Korean Ceramic Society
Volume61
Issue number3
DOIs
StatePublished - May 2024
Externally publishedYes

Bibliographical note

Publisher Copyright:
© The Korean Ceramic Society 2024.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Electrochemical water splitting
  • Metal chalcogens
  • Metallic sulfide and selenides
  • Oxygen evolution reaction (OER)

ASJC Scopus subject areas

  • Ceramics and Composites

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