Facile synthesis of MOF-derived carbon-supported LaZn@C nanocomposite as an efficient electrode material for supercapacitor

Muhammad Younis Qasim, Tauseef Munawar*, Mohammed Mujahid Alam, Chang Feng Yan, Abdullah G. Al-Sehemi, Faisal Mukhtar, Abdul Waheed Rabbani, Usman Ali Akbar, Abbas Saeed Hakeem, Faisal Iqbal

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

MOF-derived transition metal alloys have attracted researcher's interest in energy storage devices due to their vast surface area, high porosity, adjustable pore sizes, ease of modification, abundant active sites, and 3D tunable structure. Metal alloys covered with carbon can stabilize conductivity and ease charge accumulation, and they are suitable candidates for electrode materials for supercapacitor application. In this research article, core-shell LaZn@C nanocomposites were fabricated at different pyrolysis times via a hydrothermal approach. The materials that pyrolysis for two hours have a remarkable specific capacitance of 1024 F g−1 at 1 A g−1 and an impressive energy density of 36.9 Whkg−1. In addition, it has lower Rp∼0.8 Ω and Rs∼0.2 Ω resistance due to the large surface area's high carbon content with cylindrical particles. Moreover, it shows an outstanding retention rate of (94.5 % over 4500 cycles at 1 A g−1). Finally, this research showed the novelty of advanced MOF-derived materials that suggest an efficient electrode material for the electrochemical performance of energy storage devices and supercapacitor applications.

Original languageEnglish
Article number176402
JournalJournal of Alloys and Compounds
Volume1007
DOIs
StatePublished - 5 Dec 2024

Bibliographical note

Publisher Copyright:
© 2024 Elsevier B.V.

Keywords

  • Cylindrical shape particles
  • Hydrothermal
  • LaZn@C
  • MOF-derived
  • Pseudocapacitor

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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