TY - JOUR
T1 - Facile synthesis of MOF-derived carbon-supported LaZn@C nanocomposite as an efficient electrode material for supercapacitor
AU - Qasim, Muhammad Younis
AU - Munawar, Tauseef
AU - Alam, Mohammed Mujahid
AU - Yan, Chang Feng
AU - Al-Sehemi, Abdullah G.
AU - Mukhtar, Faisal
AU - Rabbani, Abdul Waheed
AU - Akbar, Usman Ali
AU - Hakeem, Abbas Saeed
AU - Iqbal, Faisal
N1 - Publisher Copyright:
© 2024 Elsevier B.V.
PY - 2024/12/5
Y1 - 2024/12/5
N2 - MOF-derived transition metal alloys have attracted researcher's interest in energy storage devices due to their vast surface area, high porosity, adjustable pore sizes, ease of modification, abundant active sites, and 3D tunable structure. Metal alloys covered with carbon can stabilize conductivity and ease charge accumulation, and they are suitable candidates for electrode materials for supercapacitor application. In this research article, core-shell LaZn@C nanocomposites were fabricated at different pyrolysis times via a hydrothermal approach. The materials that pyrolysis for two hours have a remarkable specific capacitance of 1024 F g−1 at 1 A g−1 and an impressive energy density of 36.9 Whkg−1. In addition, it has lower Rp∼0.8 Ω and Rs∼0.2 Ω resistance due to the large surface area's high carbon content with cylindrical particles. Moreover, it shows an outstanding retention rate of (94.5 % over 4500 cycles at 1 A g−1). Finally, this research showed the novelty of advanced MOF-derived materials that suggest an efficient electrode material for the electrochemical performance of energy storage devices and supercapacitor applications.
AB - MOF-derived transition metal alloys have attracted researcher's interest in energy storage devices due to their vast surface area, high porosity, adjustable pore sizes, ease of modification, abundant active sites, and 3D tunable structure. Metal alloys covered with carbon can stabilize conductivity and ease charge accumulation, and they are suitable candidates for electrode materials for supercapacitor application. In this research article, core-shell LaZn@C nanocomposites were fabricated at different pyrolysis times via a hydrothermal approach. The materials that pyrolysis for two hours have a remarkable specific capacitance of 1024 F g−1 at 1 A g−1 and an impressive energy density of 36.9 Whkg−1. In addition, it has lower Rp∼0.8 Ω and Rs∼0.2 Ω resistance due to the large surface area's high carbon content with cylindrical particles. Moreover, it shows an outstanding retention rate of (94.5 % over 4500 cycles at 1 A g−1). Finally, this research showed the novelty of advanced MOF-derived materials that suggest an efficient electrode material for the electrochemical performance of energy storage devices and supercapacitor applications.
KW - Cylindrical shape particles
KW - Hydrothermal
KW - LaZn@C
KW - MOF-derived
KW - Pseudocapacitor
UR - http://www.scopus.com/inward/record.url?scp=85203431700&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2024.176402
DO - 10.1016/j.jallcom.2024.176402
M3 - Article
AN - SCOPUS:85203431700
SN - 0925-8388
VL - 1007
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
M1 - 176402
ER -